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Determine the molarity of an \(\mathrm{H}_{2} \mathrm{SO}_{4}\), solution, \(15.0 \mathrm{ml}\) of which is completely neutralized by \(26.5 \mathrm{ml}\) of \(0.100 \mathrm{M}\) \(\mathrm{NaOH}\).

Short Answer

Expert verified
The molarity of the Hâ‚‚SOâ‚„ solution is approximately \(0.0883 \text{M}\).

Step by step solution

01

Calculate the moles of NaOH used in the reaction

First, we need to calculate the number of moles of NaOH that were used to neutralize the 15.0 ml of the H₂SO₄ solution. To do this, we'll use the volume and molarity of the NaOH solution: Moles of NaOH = volume (in L) × molarity Convert the volume of NaOH solution from ml to L: \(26.5 ml = \frac{26.5}{1000} = 0.0265 L\) Now, calculate the moles of NaOH: Moles of NaOH = \(0.0265 L × 0.100 M = 0.00265 \text{ moles}\)
02

Calculate the moles of Hâ‚‚SOâ‚„

Now, we can use the balanced chemical equation to find the moles of H₂SO₄ that reacted with the NaOH: 1 mole of H₂SO₄ reacts with 2 moles of NaOH. So, using the moles of NaOH, we can determine the moles of H₂SO₄: Moles of H₂SO₄ = 0.00265 moles of NaOH × \(\frac{1 \text{ mole of H₂SO₄}}{2 \text{ moles of NaOH}} = 0.001325 \text{ moles of H₂SO₄}\)
03

Calculate the molarity of Hâ‚‚SOâ‚„

Finally, we can use the moles of Hâ‚‚SOâ‚„ and the volume of the solution to determine the molarity of the Hâ‚‚SOâ‚„ solution. Again, convert the volume of Hâ‚‚SOâ‚„ solution from ml to L: \(15.0 ml = \frac{15.0}{1000} = 0.0150 L\) Now, calculate the molarity of Hâ‚‚SOâ‚„: Molarity of Hâ‚‚SOâ‚„ = \( \frac{\text{moles of Hâ‚‚SOâ‚„}}{\text{volume of Hâ‚‚SOâ‚„ solution in L}} = \frac{0.001325 \text{ moles}}{0.0150 \text{ L}} = 0.0883 \text{M} \) So, the molarity of the Hâ‚‚SOâ‚„ solution is approximately 0.0883 M.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Neutralization Reaction
In any chemical reaction where an acid and a base come together, you're dealing with neutralization. This occurs when the acid and base react to form water and a salt. In our given exercise, sulfuric acid (\(\mathrm{H}_{2}\mathrm{SO}_{4}\)) is neutralized by sodium hydroxide (\(\mathrm{NaOH}\)). This means that the \(\mathrm{H}_{2}\mathrm{SO}_{4}\) loses its acidic properties by combining with \(\mathrm{NaOH}\) to yield water and a salt, which in this case is sodium sulfate.

Neutralization reactions are essential in titrations, a common laboratory technique used to determine the concentration of an unknown solution. The reaction is completed when the number of moles of acid is equal to the number of moles of base, known as the point of equivalence.

In this exercise, the equivalence point is reached when \(15.0 \, \mathrm{ml}\) of \(\mathrm{H}_{2}\mathrm{SO}_{4}\) is completely neutralized by \(26.5 \, \mathrm{ml}\) of \(0.100 \, \mathrm{M}\) \(\mathrm{NaOH}\). Understanding this point gives us the ability to calculate other characteristics of the reaction.
Hâ‚‚SOâ‚„ Calculation
Calculating the amount or molarity of sulfuric acid (\(\mathrm{H}_{2}\mathrm{SO}_{4}\)) necessitates understanding its reaction with a base like sodium hydroxide (\(\mathrm{NaOH}\)). In our scenario, we want to find the molarity of the \(\mathrm{H}_{2}\mathrm{SO}_{4}\) solution. This involves using the amount of \(\mathrm{NaOH}\) that neutralizes the given amount of \(\mathrm{H}_{2}\mathrm{SO}_{4}\).

Here's a straightforward way to think about it:
  • First, convert the volume of \(\mathrm{NaOH}\) from \(\mathrm{ml}\) to \(\mathrm{L}\), since molarity is measured in moles per liter. This step ensures consistency in units for later calculations.
  • With the volume in \(\mathrm{L}\), multiply by the molarity of \(\mathrm{NaOH}\) to find the moles of \(\mathrm{NaOH}\) used in the reaction.
  • Using the stoichiometry of the balanced chemical equation, you can then calculate the moles of \(\mathrm{H}_{2}\mathrm{SO}_{4}\)/reacted.
By accurately following these steps, you establish a basis for precisely calculating the concentration of your acid solution.
Chemical Stoichiometry
Chemical stoichiometry is like a recipe, guiding us in understanding how much of each reactant is needed to produce a certain amount of product. In the neutralization of \(\mathrm{H}_{2}\mathrm{SO}_{4}\) by \(\mathrm{NaOH}\), stoichiometry helps us deduce the relationship between these two chemicals.

According to the balanced equation:
  • \(1\) mole of \(\mathrm{H}_{2}\mathrm{SO}_{4}\) reacts with \(2\) moles of \(\mathrm{NaOH}\).
Knowing this ratio helps us calculate how much \(\mathrm{H}_{2}\mathrm{SO}_{4}\) is required or produced when interacting with a known amount of \(\mathrm{NaOH}\).
  • For every \(0.00265\) moles of \(\mathrm{NaOH}\), there will be \(0.001325\) moles of \(\mathrm{H}_{2}\mathrm{SO}_{4}\).
  • The stoichiometry provides a crucial step in determining concentrations and other characteristics of reactants and products in the chemical reaction.
Understanding this equation empowers you in calculating and predicting going forward in any such titration and analysis.
Solution Concentration
Understanding solution concentration is essential as it allows you to describe the amount of solute - in this case, \(\mathrm{H}_{2}\mathrm{SO}_{4}\) - dissolved in a solvent, typically water. The most common way to express concentration is through molarity, noted as \(\mathrm{M}\), which is moles per liter (\(\mathrm{mol/L}\)).

In our example, the goal is to find the molarity of the \(\mathrm{H}_{2}\mathrm{SO}_{4}\) solution.
  • The concentration helps us determine how strong or dilute the acid solution is.
  • The formula to find molarity is \(\text{Molarity} = \frac{\text{moles}}{\text{volume in L}}\).
This particular exercise determined that \(0.001325\) moles of \(\mathrm{H}_{2}\mathrm{SO}_{4}\) are present in \(0.0150 \, \mathrm{L}\) of solution.

The resulting molarity of \(\mathrm{H}_{2}\mathrm{SO}_{4}\) is\(0.0883\) \(\mathrm{M}\). Calculating molarity not only allows scientists to understand solution properties but also facilitates informed reactions preparation and analysis.

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Most popular questions from this chapter

A chemist wants the percent dissociation of \(\mathrm{HC}_{2} \mathrm{H}_{3} \mathrm{O}_{2}\) to be \(1 \%\). If the \(\mathrm{K}_{\text {diss }}\) of \(\mathrm{HC}_{2} \mathrm{H}_{3} \mathrm{O}_{2}\) is \(1.8 \times 10^{-5}\), what concentration of \(\mathrm{HC}_{2} \mathrm{H}_{3} \mathrm{O}_{2}\) is required?

One of the two most common ingredients in medication designed for the relief of excess stomach acidity is aluminum hydroxide ( \(\mathrm{Al}(\mathrm{OH})_{3}\), formula weight \(=78 \mathrm{~g} / \mathrm{mole}\) ). If a patient suffering from a duodenal ulcer displays a hydrochloric acid (HCI, formula weight \(=36.5 \mathrm{~g} /\) mole \(),\) concentration of \(80 \times\) \(10^{-3} \mathrm{M}\) in his gastric juice and he produces 3 liters of gastric juice per day, how much medication containing \(2.6 \mathrm{~g} \mathrm{Al}(\mathrm{OH})_{3}\) per \(100 \mathrm{ml}\) of solution must he consume per day to neutralize the acid?

A \(0.10 \mathrm{M}\) solution of \(\mathrm{HCl}\) is prepared. What species of ions are present at equilibrium, and what will be their equilibrium concentrations?

The ionization constant for \(\mathrm{NH}_{4} \mathrm{OH}\) is \(1.8 \times 10^{-5}\). (a) Calculate the concentration of \(\mathrm{OH}^{-}\) ions in a \(1.0\) molar solution of \(\mathrm{NH}_{4} \mathrm{OH}\).

For the complex ion equilibrium for the dissociation of \(\mathrm{Cu}\left(\mathrm{NH}_{3}\right)^{2}{ }_{4}^{+}\), calculate (1) the ratio of \(\mathrm{Cu}^{2+}\) ion to \(\mathrm{Cu}\left(\mathrm{NH}_{3}\right)^{2}{ }_{4}^{+}\) in a solution \(1 \mathrm{M}\) in \(\mathrm{NH}_{3} ;\) (2) the equilibrium concentration of \(\mathrm{NH}_{3}\) needed to attain \(50 \%\) conversion of \(\mathrm{Cu}^{2+}\) to \(\mathrm{Cu}\left(\mathrm{NH}_{3}\right)^{2}{ }_{4}^{+}\) \(\mathrm{K}_{\mathrm{a}}\) for \(\mathrm{Cu}\left(\mathrm{NH}_{3}\right)^{2}{ }_{4}^{+}=2 \times 10^{-13}\)

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