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What is the \(\mathrm{pH}\) value of \(0.001 \mathrm{M} \mathrm{HCl}\) solution?

Short Answer

Expert verified
The pH is 3.

Step by step solution

01

Understanding the Problem

A solution's pH is calculated using the concentration of hydrogen ions ( [H鈦篯). Hydrochloric acid (HCl) is a strong acid, which means it dissociates completely in water. Therefore, the concentration of H鈦 ions in a 0.001 M solution of HCl is also 0.001 M.
02

Applying the pH Formula

The formula for calculating pH is \(\mathrm{pH} = -\log_{10}[\mathrm{H}^+]\), where [\mathrm{H}^+] is the concentration of hydrogen ions in moles per liter.
03

Calculate the pH

Substitute the concentration of hydrogen ions into the pH formula: \(\mathrm{pH} = -\log_{10}(0.001)\). The logarithm base 10 of 0.001 is -3, therefore \(\mathrm{pH} = -(-3) = 3\).
04

Confirm the Calculation

Verify the calculation: \(\mathrm{pH} = 3\) makes sense because 0.001 M HCl is a diluted solution, and strong acids will have lower pH values than a neutral solution (which has a pH of 7).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Hydrogen Ion Concentration
To understand the pH of a solution, it is crucial to comprehend what hydrogen ion concentration means. When we talk about hydrogen ion concentration, we're referring to the amount of hydrogen ions, (H鈦), present in a solution. This is usually expressed in moles per liter (Molarity, or simply M).

In solutions of acids, hydrogen ions ( H鈦) come from the dissociation of the acid molecules. For instance, when hydrochloric acid ( HCl) is dissolved in water, it breaks up entirely into hydrogen ions ( H鈦) and chloride ions ( Cl鈦).

This characteristic is marked in strong acids, like hydrochloric acid, which dissociate completely. Therefore, the concentration of containing hydrogen ions directly reflects the initial concentration of the acid in solution. Knowing this is critical for calculating the pH, as the pH formula depends on this value.
Strong Acids
Strong acids are a class of acids known for their complete dissociation when mixed with water. This means that strong acids will fully separate into their individual ions, yielding a high concentration of hydrogen ions ( H鈦).

Hydrochloric acid ( HCl) is a prime example of a strong acid. When dissolved in water, it separates totally into hydrogen ions ( H鈦) and chloride ions ( Cl鈦). This complete ionization is what enables strong acids to alter the pH of a solution drastically even at relatively low concentrations.

  • Strong acids always dissociate fully, releasing H鈦 ions into the solution.
  • They frequently result in low pH values due to the high concentration of hydrogen ions produced.
  • The pH of a strong acid solution is directly linked to its hydrogen ion concentration.
Example: If you have a 0.001 M solution of HCl, the concentration of H鈦 ions is also 0.001 M due to complete dissociation.
Logarithmic Equations
Logarithmic equations play a pivotal role in determining the pH of a solution. The term "logarithmic" refers to the use of logarithms, which are the inverse operation to exponentiation.

In the context of pH, the formula \(\mathrm{pH} = -\log_{10}[\mathrm{H}^+]\) employs the base 10 logarithm. Here's how it works:

  • The logarithm base 10 of a number is the exponent by which 10 must be raised to yield that number.
  • This means that \(\log_{10}(0.001) = -3\), because \(10^{-3} = 0.001\).
  • Thus, taking negation leads to a pH of 3 for a 0.001 M HCL solution.
This logarithmic relationship helps us understand changes in hydrogen ion concentration more accurately. Because pH is a logarithmic scale, each one-unit change reflects a tenfold change in hydrogen ion concentration. Thus, logarithmic equations are essential for conveying the wide range of hydrogen ion concentrations in a simplified, understandable manner.

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