Chapter 11: Problem 3
Draw the structure of each of the following fatty acids, and give the structure its common name. (a) \(n\) -Dodecanate (b) \(c i s-\Delta^{9}\) -Hexadecenoate (c) \(c i s, c i s-\Delta^{9}, \Delta^{12}\) - Octadecadienoate
Short Answer
Expert verified
(a) Laurate, (b) Palmitoleate, (c) Linoleate.
Step by step solution
01
Identify the Type of Fatty Acid
To start, identify the chain length and saturation/unsaturation from the name. For example, 'n-Dodecanate' indicates a saturated fatty acid with a chain length of 12 carbon atoms.
02
Draw the Structure of n-Dodecanate
Draw a straight carbon chain with 12 carbon atoms (since it's dodecanate). Attach a carboxylate group (-COO鈦) to the terminal carbon (n-position) and fill in the hydrogen atoms to satisfy the tetravalence of carbon. The common name for this structure is Laurate.
03
Identify the Unsaturation in 肠颈蝉-螖鈦-贬别虫补诲别肠别苍辞补迟别
Hexadecenoate indicates a 16-carbon chain with one double bond. The term 'cis-螖鈦' specifies that the double bond is at the 9th carbon and it is in the cis configuration.
04
Draw the Structure of 肠颈蝉-螖鈦-贬别虫补诲别肠别苍辞补迟别
Begin by drawing a 16-carbon chain. Locate the 9th carbon and introduce a cis double bond (the two hydrogens attached to the carbons in the double bond are on the same side). Add a carboxylate group to the first carbon. This fatty acid is commonly called Palmitoleate.
05
Identify the Unsaturation in 肠颈蝉,肠颈蝉-螖鈦,螖鹿虏-翱肠迟补诲别肠补诲颈别苍辞补迟别
Octadecadienoate suggests an 18-carbon chain with two double bonds. 'cis, cis-螖鈦, 螖鹿虏' indicates that there are cis double bonds at the 9th and 12th carbons.
06
Draw the Structure of 肠颈蝉,肠颈蝉-螖鈦,螖鹿虏-翱肠迟补诲别肠补诲颈别苍辞补迟别
Draw an 18-carbon chain and insert cis double bonds at positions 9 and 12. Attach a carboxylate group to the first carbon in the chain. The common name for this structure is Linoleate.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
n-Dodecanate
Understanding fatty acids starts with knowing their structure. **n-Dodecanate** is a saturated fatty acid, meaning all carbon-carbon bonds are single bonds. This particular fatty acid is composed of a chain of 12 carbon atoms, which is typical for what we call a 'dodecanoic acid'. Hence the prefix 'n' indicates its straight-chain nature.
- Dodecanate has a special common name: Laurate.
- The structure includes a carboxylate group (-COO鈦), signifying its fatty acid identity.
肠颈蝉-螖鈦-贬别虫补诲别肠别苍辞补迟别
**肠颈蝉-螖鈦-贬别虫补诲别肠别苍辞补迟别** brings us to the realm of unsaturated fatty acids. Here, the name tells us a lot: 'hexadecenoate' suggests a fatty acid with 16 carbon atoms and 'enoate' hints at a double bond. The 'cis-螖鈦' specifically indicates the position and configuration of this double bond.
- 'Cis' means that the hydrogen atoms attache to the marketed carbons are on the same side, introducing a noticeable kink in the chain.
- This fatty acid is better known as Palmitoleate.
肠颈蝉,肠颈蝉-螖鈦,螖鹿虏-翱肠迟补诲别肠补诲颈别苍辞补迟别
Venturing further, **肠颈蝉,肠颈蝉-螖鈦,螖鹿虏-翱肠迟补诲别肠补诲颈别苍辞补迟别** represents an unsaturated fatty acid with multiple double bonds, specifically two. The name unfolds the presence of 18 carbons, as indicated by 'octadecadienoate', and gives hints about the double bond locations and configurations ('cis').
- Each 'cis' indicates the same-side placement of hydrogen atoms, adding two kinks more pronounced into the fatty acid's structure, particularly at the 9th and 12th carbon positions.
- The common name you might recognize is Linoleate.