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What will be the composition of the effluent when a dilute solution of each of the following is passed through a cation exchange column in the hydrogen form? (a) \(\mathrm{NaCl}\); (b) \(\mathrm{Na}_{2} \mathrm{SO}_{4} ;\) (c) \(\mathrm{HClO}_{4}\); (d) \(\mathrm{FeSO}_{4} ;\left(\mathrm{NH}_{4}\right)_{2} \mathrm{SO}_{4}\).

Short Answer

Expert verified
Effluents: (a) HCl; (b) H鈧係O鈧; (c) mostly HClO鈧; (d) H鈧係O鈧, FeCl鈧.

Step by step solution

01

Understanding Cation Exchange Principles

A cation exchange column in the hydrogen form will exchange cations in the incoming solution with hydrogen ions in the resin. Thus, the effluent will contain the anions from the incoming solution combined with the hydrogen ions from the resin exchange.
02

Analyzing Effluent for NaCl Solution

For NaCl solution, sodium ions (Na鈦) are replaced by hydrogen ions (H鈦) in the resin. The effluent will contain HCl, the chloride ions from NaCl combined with the exchanged H鈦 from the resin.
03

Analyzing Effluent for Na鈧係O鈧 Solution

For Na鈧係O鈧 solution, each sodium ion (Na鈦) is replaced by a hydrogen ion (H鈦), leading to the formation of H鈧係O鈧 (since each sulfate ion SO鈧劼测伝 will combine with two H鈦 ions from the resin exchange).
04

Analyzing Effluent for HClO鈧 Solution

HClO鈧 is already an acid, and the cation exchange column will theoretically remove H鈦, but practical application sees negligible effect as the H鈦 involved is exchanged back to form HClO鈧 in the effluent.
05

Analyzing Effluent for FeSO鈧 and (NH鈧)鈧係O鈧 Solutions

Both iron (Fe虏鈦) and ammonium (NH鈧勨伜) ions in the mixture will be replaced by hydrogen ions (H鈦). The effluent will contain H鈧係O鈧 from (SO鈧劼测伝 combining with H鈦), FeCl鈧 and water resulting from exchange of hydrogen ions with Fe虏鈦 and NH鈧勨伜 ions respectively.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Hydrogen Ion Exchange
Hydrogen ion exchange is a vital process in chemistry, particularly in water treatment and purification. When a solution passes through a cation exchange column filled with a resin in its hydrogen form, the resin will swap out any cations (positively charged ions) in the solution for hydrogen ions (\(H^+\)). This process is effective for removing unwanted cations and replacing them with hydrogen ions, leading to a purified solution. Thus, the incoming cations get exchanged for hydrogen ions, transforming the original salts or bases into their acidic forms, contributing to a purification effect.
For instance, when a sodium chloride (\(NaCl\)) solution passes through a cation exchange column, the \(Na^+\) ions are replaced with \(H^+\) ions. The result is an effluent primarily composed of hydrochloric acid (\(HCl\)). This transformation exemplifies the cation to hydrogen exchange process.
  • Efficient for removing metal ions.
  • Converts salts to corresponding acids.
  • Used in various chemical and industrial processes.
Ion Exchange Column
An ion exchange column is a crucial component in many purification and separation processes. It resembles a cylinder packed with a resin capable of exchanging ions - either cations or anions depending on its form. This column harnesses the principle of ion exchange to specifically target undesired ions in a solution, replacing them with others that the resin holds.
In the case of cation exchange, the column contains resin beads in their hydrogen form. When a solution passes through such a column, ions in the solution are swapped for hydrogen ions held in the resin. This can effectively alter the chemical composition of the solution.
  • Used for water purification and softening.
  • Can handle large volumes of solution.
  • Vital in chemical analysis and preparation.
Effluent Composition
Effluent composition refers to the types of ions and molecules present in a liquid that exits an ion exchange system. After the ion exchange has taken place, the effluent will reflect the converted state of the solution, showing a different ionic makeup than what was originally introduced. In the context of a hydrogen-form cation exchange, the effluent's main constituents are hydrogen ions and whatever anions were originally paired with the swapped-out cations.
Taking the example of a sodium sulfate (\(Na_2SO_4\)) solution passing through a cation exchange column, sodium ions are exchanged for hydrogen ions, leading to an effluent enriched with sulfuric acid (\(H_2SO_4\)). Monitoring effluent composition is crucial for ensuring the effectiveness of the exchange process and the quality of the purified solution.
  • Indicates effectiveness of ion exchange.
  • Essential for process optimization.
  • Varies based on incoming solution.
Resin
In ion exchange processes, resin plays a pivotal role in facilitating the transfer of ions. These resins are polymer-based substances capable of swapping specific ions within a solution for those held by the resin beads. The selection of resin determines the type of ion exchange, be it cation or anion. In a cation exchange system, like in the hydrogen form, the resin beads hold onto hydrogen ions ready to exchange them with cations from the solution.
Resins are typically designed to maximize interaction with the solution, ensuring efficient ion exchange. They are robust, long-lasting, and can be regenerated for repeated use, making them cost-effective.
  • Highly effective at selecting specific ions.
  • Can be tailored to specific applications.
  • Regeneration allows for prolonged use.
Anion Exchange
Anion exchange is the counterpart to cation exchange, primarily dealing with the removal and replacement of anions in a solution. In contrast to cation exchange that swaps cations for hydrogen ions, anion exchange columns are designed to replace anions with hydroxide ions (\(OH^-\)) or other desired ions. This process is critical for targeting and eliminating specific anionic contaminants or for adjusting the pH of a solution.
Anion exchange is frequently applied in processes like demineralization, desalination, and chemical synthesis. While it wasn't directly involved in the original exercise that focused on hydrogen ion exchange, understanding both types of ion exchange is fundamental for grasping how various ions can be manipulated within a chemical process.
  • Targets anionic impurities.
  • Essential for balancing solution chemistry.
  • Widely implemented in advanced water treatment.

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