Chapter 8: Problem 245
\(1.75 \mathrm{gm}\) of solid \(\mathrm{NaOH}\) are added to \(250 \mathrm{ml}\) of \(0.1 \mathrm{M}\) \(\mathrm{NiCl}_{2}\) solution. Calculate the approximate \(\mathrm{pH}\) of final solution. \(\left(\mathrm{K}_{\mathrm{sp}}\right.\) of \(\left.\mathrm{Ni}(\mathrm{OH})_{2}=1.6 \times 10^{-14}\right)\).
Short Answer
Step by step solution
Determine Moles of NaOH
Determine Moles of NiCl2
Write Reaction Equation
Determine Limiting Reagent
Calculate Remaining Species
Calculate Concentration of OH-
Calculate [Ni^2+]
Verify with K_sp
Calculate New OH- Concentration
Calculate pH
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Moles of NaOH
First, we find the molar mass of NaOH. Sodium hydroxide (NaOH) has a molar mass of about 40 g/mol. This means each mole of NaOH weighs 40 grams. When you have 1.75 grams of NaOH, you can convert this to moles by dividing the mass by the molar mass.
The calculation is: \[ ext{Moles of NaOH} = \frac{1.75 ext{ g}}{40 ext{ g/mol}} = 0.04375 ext{ mol} \]This shows you that in this exercise, we are starting with 0.04375 moles of NaOH. This foundational knowledge is essential for proceeding with any calculations involving chemical reactions.
Limiting Reagent
In the reaction between NaOH and NiCl\( _2 \) \[ ext{NiCl}_2 + 2 ext{NaOH} \rightarrow ext{Ni(OH)}_2 \downarrow + 2 ext{NaCl} \]we see that it takes 2 moles of NaOH to fully react with 1 mole of NiCl\(_2 \).
Given we have 0.025 moles of NiCl\(_2 \) and 0.04375 moles of NaOH, we need 0.050 moles of NaOH to completely react with the NiCl\(_2 \).
However, since we only have 0.04375 moles of NaOH, NaOH is the limiting reagent. It limits how far the reaction can go because we will run out of NaOH before we use all the NiCl\(_2 \). Understanding which reagent is limiting helps us determine the maximum amount of product that can be formed.
Reaction Equation
The equation tells us that for every mole of nickel chloride (NiCl\(_2 \)) that reacts, two moles of sodium hydroxide (NaOH) are consumed, producing one mole of nickel hydroxide (Ni(OH)\(_2 \)) and two moles of sodium chloride (NaCl).
The arrow indicates the direction of the reaction, showing that the compounds on the left (reactants) turn into those on the right (products). The downward arrow next to Ni(OH)\(_2 \) signifies that it is a precipitate, meaning it forms a solid in the mixture which can separate out of the solution. Using the equation helps in predicting the amount of product formed and knowing the reactants' relationships.