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In liquid \(\mathrm{CCl}_{4}\) which of the following has maximum solubility? (a) \(\mathrm{I}_{2}\) (b) \(\mathrm{Br}_{2}\) (c) \(\mathrm{NaCl}\) (d) \(\mathrm{Cl}_{2}^{2}\)

Short Answer

Expert verified
\( \mathrm{I}_{2} \) has maximum solubility in \( \mathrm{CCl}_{4} \).

Step by step solution

01

Identify the Solvent

The problem states that the solvent is liquid carbon tetrachloride, \( \mathrm{CCl}_{4} \). This is a non-polar solvent, meaning that it dissolves non-polar solutes well due to the principle that 'like dissolves like.'
02

Determine Polarity of Solutes

Analyze the polarity of each solute: \- \( \mathrm{I}_{2} \) and \( \mathrm{Br}_{2} \) are homonuclear diatomic molecules and non-polar. \- \( \mathrm{NaCl} \), an ionic compound, is polar. \- \( \mathrm{Cl}_{2}^{2} \) is a non-existent entity in this form; likely intended \( \mathrm{Cl}_{2} \), which is non-polar.
03

Apply Solubility Principle

Since \( \mathrm{CCl}_{4} \) is non-polar, non-polar solutes will have greater solubility. Therefore, \( \mathrm{I}_{2}, \mathrm{Br}_{2}, \) and the corrected \( \mathrm{Cl}_{2} \) would be more soluble than \( \mathrm{NaCl} \) in \( \mathrm{CCl}_{4} \).
04

Compare Solubility of Non-Polar Solutes

To determine which non-polar solute has maximum solubility in \( \mathrm{CCl}_{4} \), consider molecular size. Larger non-polar molecules generally exhibit higher solubility due to their larger electron cloud. Hence, \( \mathrm{I}_{2} \), being larger than \( \mathrm{Br}_{2} \) and \( \mathrm{Cl}_{2} \), will have the maximum solubility.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Non-Polar Solvents
Non-polar solvents like carbon tetrachloride (CClâ‚„) do not have a significant charge difference between their atoms. This means that the electrons are evenly distributed around the molecule. Most of these solvents are made up of atoms with similar electronegativities, which prevents the formation of strong partial charges. As a result, non-polar solvents are excellent at dissolving non-polar substances.

In the original exercise, carbon tetrachloride is a classic example of a non-polar solvent. It is particularly effective at dissolving substances that do not have an overall charge, such as iodine (Iâ‚‚) and bromine (Brâ‚‚). These molecules maintain an even distribution of their electrons just like CClâ‚„, making them highly compatible with the solvent.

Non-polar solvents are often used in industrial applications for dissolving oils, fats, and other organic compounds. Because they do not dissolve ionic or polar substances well, they are also helpful in separating components based on polarity.
Polarity of Molecules
In chemistry, a molecule's polarity refers to how its electrons are shared among its atoms, and this affects how it interacts with other molecules. Molecules can be classified as polar or non-polar.

Polar molecules have uneven electron distribution, resulting in one part of the molecule having a slight positive charge and another part a slight negative charge. This happens when there is a significant difference in electronegativity between the atoms involved in a bond. For example, water (Hâ‚‚O) is a well-known polar molecule due to the oxygen-hydrogen electronegativity difference.

On the other hand, non-polar molecules have electrons spread out evenly across the molecule. This occurs when atoms with similar electronegativities form bonds, as is the case with hydrogen gas (Hâ‚‚) or iodine (Iâ‚‚). These molecules have no permanent dipole, meaning they do not readily dissolve in polar solvents.
  • Polar = uneven electron distribution
  • Non-Polar = even electron distribution, no charge difference
Understanding the polarity of molecules helps predict how they will interact with solvents, as seen in the CClâ‚„ exercise.
Principle of 'Like Dissolves Like'
The phrase "Like dissolves like" is a simple guideline in chemistry that helps predict solubility. It implies that a solvent will best dissolve substances that have a similar polarity.

For example, a polar solvent such as water will dissolve polar substances like salt (NaCl) or sugar, owing to their charge interactions. Meanwhile, non-polar solvents, such as CClâ‚„ or hexane, will favor non-polar solutes like oils or gases like oxygen. This principle helps chemists anticipate whether a compound will dissolve in a given solvent.

In the exercise provided, this principle is used to decide which solute will be most soluble in CClâ‚„. Since CClâ‚„ is non-polar, the non-polar molecules Iâ‚‚, Brâ‚‚, and Clâ‚‚, which share similar characteristics, are predicted to be more soluble than polar ones like NaCl.
  • "Like dissolves like": Similar polarities tend to dissolve each other.
  • Non-polar solvents dissolve non-polar solutes best.
  • Polar solvents dissolve polar solutes best.
This principle is crucial in many fields, including formulating mixtures in industries as well as selecting solvents for reactions and extractions.

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Most popular questions from this chapter

People add sodium chloride to water while boiling eggs. This is to (a) decrease the boiling point of water (b) increase the boiling point of water (c) prevent breaking of eggs (d) make eggs tasty

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An aqueous solution of a solute which nerther assoc1ates nor dissociates has a freezing point depression of \(\mathrm{X}^{\circ} \mathrm{C}\). An equimolar solution of a second has a freezing point depression of \(4 \mathrm{X}^{\circ} \mathrm{C}\). The second solution could be a salt of formula (assuming \(100 \%\) dissociation ) (a) \(\mathrm{AB}_{2}\) (b) \(\mathrm{A}_{2} \mathrm{~B}_{2}\) (c) \(\mathrm{A}_{3} \mathrm{~B}\) (d) \(\mathrm{AB}_{3}\)

When non-zero volatile solute is dissolved in a solvent, the relative lowering of vapour pressure is equal to (a) molar fraction of solute (b) molar fraction of solvent (c) concentration of the solute in grams per liter (d) concentration of the solute in gram per \(100 \mathrm{~mL}\).

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