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An ion of a d-block element has magnetic moment 5.92 BM select the ion among the following: (a) \(\mathrm{Sc}^{3+}\) (b) \(\mathrm{Zn}^{2+}\) (c) \(\mathrm{Mn}^{2+}\) (d) \(\mathrm{Cr}^{3+}\)

Short Answer

Expert verified
The ion with the magnetic moment 5.92 BM is \( \text{Mn}^{2+} \).

Step by step solution

01

Understand the formula

The magnetic moment of an ion due to unpaired electrons is calculated using the formula: \( \mu = \sqrt{n(n+2)} \), where \( n \) is the number of unpaired electrons.
02

Determine the number of unpaired electrons corresponding to the magnetic moment

The magnetic moment given is 5.92 BM. Using the formula \( \mu = \sqrt{n(n+2)} \), we solve for \( n \). The calculated magnetic moment of 5.92 BM corresponds to \( n = 5 \), which implies there are 5 unpaired electrons.
03

Analyze the electron configuration of each ion

1. \( \text{Sc}^{3+} \): \([\text{Ar}] \), 0 unpaired electrons.2. \( \text{Zn}^{2+} \): \([\text{Ar}]3d^{10}\), 0 unpaired electrons.3. \( \text{Mn}^{2+} \): \([\text{Ar}]3d^5\), 5 unpaired electrons.4. \( \text{Cr}^{3+} \): \([\text{Ar}]3d^3\), 3 unpaired electrons.
04

Select the ion with the correct number of unpaired electrons

Among the given ions, \( \text{Mn}^{2+} \) has 5 unpaired electrons, which matches the required condition as calculated from the magnetic moment formula \( \mu = 5.92\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Unpaired Electrons
Unpaired electrons play a crucial role in determining the magnetic properties of an element or ion. These electrons are those that are not paired with another electron with opposite spin in an atom's subshells. In simple terms, when electrons are singly occupied in their orbitals, they are considered unpaired.

Unpaired electrons contribute to the magnetic moment of a substance. A substance with more unpaired electrons will generally have a stronger magnetic moment, often making it paramagnetic. On the other hand, if all electrons in an atom or ion are paired, the magnetic fields generated cancel each other out, resulting in a non-magnetic material.

Because of these properties, understanding the count of unpaired electrons can help predict and explain the behavior of an ion or molecule in a magnetic field. This is why, in exercises like determining the magnetic moment of different ions, identifying the number of unpaired electrons is a crucial step.
Electron Configuration
Electron configuration is a way of representing the distribution of electrons across the orbitals of an atom or ion. It dictates the chemical properties and reactivity of elements by illustrating how electrons are arranged in atomic orbitals.
  • The electron configuration notation consists of a series of numbers and letters (such as 1s, 2s, 2p, 3s, etc.) that indicate the energy levels, subshells, and number of electrons in those subshells.
  • For ions, electron configurations are adjusted by removing or adding electrons to the outermost shell according to the ion's charge.
Examining an element's or ion's electron configuration can provide insights into its magnetic properties and stability. For instance, the electron configuration for \( Mn^{2+} is [Ar]3d^5\), which clearly shows it has five unpaired electrons in the 3d subshell, leading to its significant magnetic moment.
D-Block Elements
D-block elements, also known as transition metals, include those elements found in groups 3 through 12 of the periodic table. A unique characteristic of these elements is the filling of their 3d, 4d, or 5d orbitals. As a result, these elements exhibit distinct properties such as variable oxidation states and colored compounds.

The d-block elements demonstrate a unique ability to form ions with different charges due to the near equal energy level of 's' and 'd' orbitals. This results in diverse magnetic and chemical behavior, particularly due to the presence of unpaired electrons in the d-orbital.
  • In these elements, the partially filled d orbitals permit electrons to remain unpaired, a necessary condition for magnetism.
  • Their electron configurations significantly influence their magnetic moment and chemical reactivity.
Understanding the behavior of d-block elements involves closely examining their electron configurations to identify any unpaired electrons, which play a crucial role in determining their magnetic properties.

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Most popular questions from this chapter

The quantum number \(+1 / 2\) and \(-1 / 2\) for the electron spin represent (a) rotation of the electron in clockwise and anticlockwise direction respectively. (b) rotation of the electron in anti clockwise and clockwise direction respectively. (c) magnetic moment of the electron pointing up and down respectively. (d) two quantum mechanical spin states which have no classical analogues.

The de Broglie wavelength associated with a particle of mass \(10^{-6} \mathrm{~kg}\) moving with a velocity of \(10 \mathrm{~ms}^{-1}\) is (a) \(6.63 \times 10^{-7} \mathrm{~m}\) (b) \(6.63 \times 10^{-16} \mathrm{~m}\) (c) \(6.63 \times 10^{-21} \mathrm{~m}\) (d) \(6.63 \times 10^{-29} \mathrm{~m}\)

Which of the following statement(s) are correct? (1) the electronic configuration of \(\mathrm{Cr}\) is \([\mathrm{Ar}] 3 \mathrm{~d}^{5} 4 \mathrm{~s}^{1}\) (atomic number of \(\mathrm{Cr}=24\) ) (2) the magnetic quantum number may have a negative value (3) in silver atom, 23 electrons have a spin of one type and 24 of the opposite type (atomic number of \(\mathrm{Ag}=47\) ) (4) the oxidation state of nitrogen in HN, is \(-3\) (a) \(1,2,3\) (b) \(2,3,4\) (c) 3,4 (d) \(1,2,4\)

The atomic number of an element is 35 . What is the total number of electrons present in all the p-orbitals of the ground state atom of that element? (a) 17 (b) 11 (c) 23 (d) 6

Which one of the following pairs of ions have the same electronic configuration? (a) \(\mathrm{Sr}^{3+}, \mathrm{Cr}^{3+}\) (b) \(\mathrm{Fe}^{3+}, \mathrm{Mn}^{2+}\) (c) \(\mathrm{Fe}^{3+}, \mathrm{Co}^{3+}\) (d) \(\mathrm{Cr}^{3+}, \mathrm{Fe}^{3+}\)

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