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\(\mathrm{K} 1\) and \(\mathrm{CuSO}_{4}\) solution when mixed gives (a) \(\mathrm{K}_{2} \mathrm{SO}_{4}+\mathrm{Cu}_{2} \mathrm{I}_{2}+\mathrm{I}_{2}\) (b) \(\mathrm{Cu}_{2} \mathrm{I}_{2}+\mathrm{K}_{2} \mathrm{SO}_{4}\) (c) \(\mathrm{CuI}_{2}+\mathrm{K}_{2} \mathrm{SO}_{4}\) (d) \(\mathrm{K}_{2} \mathrm{SO}_{4}+\mathrm{CuI}_{2}+\mathrm{I}_{2}\)

Short Answer

Expert verified
The correct answer is (a) K鈧係O鈧 + Cu鈧侷鈧 + I鈧.

Step by step solution

01

Identify the Reactants

The reactants given in the exercise are K (potassium) and CuSO鈧 (copper(II) sulfate). These will be mixed to find the products.
02

Determine the Possible Products

When K and CuSO鈧 react, they can potentially form K鈧係O鈧 (potassium sulfate) and copper iodide compounds as part of the double displacement reaction. To get all possible combinations, the complete reaction should also consider the formation of CuI鈧 (copper(II) iodide) or Cu鈧侷鈧 (copper(I) iodide) and iodine (I鈧).
03

Balance the Reaction

Consider the double displacement reaction: 1. Replace the sulfate ion with K to form K鈧係O鈧. 2. The remaining compound could result in Cu鈧侷鈧 along with I鈧 (since I can also combine to form I鈧 molecules as a result of change in oxidation state from Cu虏鈦 to Cu鈦).
04

Evaluate the Options

The correct answer includes both iodide and iodine molecules as well as potassium sulfate. The compound with copper might exist in the form Cu鈧侷鈧 (copper(I) iodide) due to possible disproportionation of Cu(I) to Cu(II) and Cu. Among the choices, option (a) includes Cu鈧侷鈧, K鈧係O鈧, and I鈧.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Copper(I) Iodide
Copper(I) Iodide is a compound where copper exists in the +1 oxidation state. It is often represented as Cu鈧侷鈧. Copper has two main oxidation states: +1 and +2. In Cu鈧侷鈧, each copper atom shares iodine with another copper atom, resulting in a dual copper presence. This structure differs from copper(II) iodide, where copper exists in the +2 state. Understanding the differences in oxidation states is crucial, as it affects the stability and predictability of reactions.
In chemical reactions like the one in the exercise, the formation of Cu鈧侷鈧 is based on copper鈥檚 ability to disproportionate. Disproportionation occurs when an element in one oxidation state is simultaneously oxidized and reduced to form two different compounds.
  • Cu鈦 is oxidized to Cu虏鈦 and reduced to neutral Cu.
  • This reaction stabilization favors the creation of Cu鈧侷鈧.
Recognizing these patterns helps predict possible products in reactions such as double displacement reactions.
Double displacement reactions typically involve the exchange of ions between reactants to form new products, making this information central to determining the final product configuration.
Potassium Sulfate
Potassium sulfate, or K鈧係O鈧, is a common inorganic chemical compound used extensively as a fertilizer. Potassium sulfate is formed when potassium ions ( K鈦) exchange places with other metal ions in salts during a reaction, as seen in double displacement reactions.
This compound is stable and forms when potassium reacts with sulfate ions ( SO鈧劼测伝). In the context of a chemical equation, potassium sulfate is often the predictable outcome of a reaction involving potassium.
The formation of K鈧係O鈧 shows how ionic compounds can easily swap cations, making balancing the chemical equation straightforward. In the textbook solution, observing K鈧係O鈧 as a product reflects the movement of ions that is standard in reactions involving sulfates.
  • The potassium ion bonds with sulfate to create K鈧係O鈧.
  • Stability of K鈧係O鈧 is high, favoring its consistent appearance in these reactions.
This knowledge of potassium's affinity for pairing with sulfate ions is crucial when balancing and predicting outcomes of chemical reactions.
Balancing Chemical Equations
Balancing chemical equations is critical to accurately describe chemical reactions. It requires ensuring the number of atoms of each element is the same on both sides of the equation. The law of conservation of mass directs this balancing act, confirming that matter is neither created nor destroyed in chemical reactions.
In a balanced equation, reactants are transformed into products without the creation of additional ions or molecules that were not originally present. The textbook exercise shows an example where potassium and copper sulfate react to form new compounds, needing precise balance to reflect reality.
  • Identify each reactant and product involved.
  • Use coefficients to balance each element across the equation.
For instance, if Cu鈧侷鈧 and I鈧 are products, coefficients need adjusting to balance iodine on both sides. This process ensures the theory aligns with experimental results, showcasing the precision needed in chemistry.
Ultimately, mastering balancing techniques strengthens understanding of chemical reaction dynamics, providing a strong foundation for more complex chemistry concepts.

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