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The nature of an aqueous solution of \(\mathrm{FeCl}_{2}\) is (a) basic (b) acidic (c) amphoteric (d) neutral

Short Answer

Expert verified
The aqueous solution of FeCl鈧 is acidic (option b).

Step by step solution

01

Identify the components

FeCl鈧 is composed of Fe虏鈦 (ferrous ion) and Cl鈦 (chloride ion). In an aqueous solution, the compound dissociates into these ions.
02

Analyze the ions

The chloride ion (Cl鈦) comes from a strong acid (HCl), and it is a neutral spectator ion in solution. The ferrous ion (Fe虏鈦) can potentially hydrolyze in water.
03

Consider hydrolysis

Fe虏鈦 can hydrolyze in water to form Fe(OH)鈦 and H鈦 ions: \[\mathrm{Fe}^{2+} + \mathrm{H}_{2}\mathrm{O} \rightleftharpoons \mathrm{Fe(OH)}^{+} + \mathrm{H}^{+}\]This reaction releases H鈦 ions, which can make the solution acidic.
04

Determine the final nature of the solution

Since the hydrolysis of Fe虏鈦 releases H鈦 ions, it causes the solution to have a higher concentration of H鈦 ions than OH鈦 ions, making the solution acidic.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Aqueous Solutions
An aqueous solution is a type of mixture where the solvent is water. In chemistry, when substances are dissolved in water, they form ions, which allows them to interact with one another.
When we talk about an aqueous solution, we often refer to both the solute (the substance being dissolved) and the solvent (water, in this case).
  • Water is known as a 'universal solvent' due to its excellent capability to dissolve numerous substances.
  • In an aqueous solution, the dissolved substance can either be ionic or molecular.
The key feature of an aqueous solution is the presence of dissolved substances, which are often completely ionized, meaning the substances break apart into their respective ions.
For example, in a solution of FeCl鈧 in water, the compound dissociates into Fe虏鈦 and Cl鈦 ions, as the exercise above describes.
Understanding the nature of these solutions helps us predict how different substances will behave when mixed with water.
Hydrolysis
Hydrolysis is a chemical process that involves the reaction of a compound with water. In the context of acid-base chemistry, it refers to the reaction of ions with water, often resulting in the formation of an acid or a base.
When Fe虏鈦 ions are placed in water, they tend to undergo hydrolysis, a reaction where they interact with water molecules.
This happens as follows where Fe虏鈦 reacts with water to form Fe(OH)鈦 and releases H鈦 ions: \[\mathrm{Fe}^{2+} + \mathrm{H}_{2}\mathrm{O} \rightleftharpoons \mathrm{Fe(OH)}^{+} + \mathrm{H}^{+}\]This reaction shows that hydrolysis can change the pH of the solution, making it more acidic due to the release of hydrogen ions.
  • Hydrolysis is significant as it can alter the chemical environment in a solution, affecting its acidity or basicity.
  • Not all ions undergo hydrolysis; it depends on their nature and the strength of their parent acids or bases.
This process is particularly important in solutions like FeCl鈧, as it explains why the solution may turn acidic due to the behavior of the Fe虏鈦 ions.
pH and Acidity
pH is a measurement of the acidity or basicity of a solution, reflecting the concentration of hydrogen ions (H鈦) present. The pH scale ranges from 0 to 14, with values below 7 indicating an acidic solution and those above 7 indicating a basic one.
Acidic solutions have higher concentrations of H鈦 ions. In contrast, basic solutions have fewer H鈦 ions, usually compensated by higher OH鈦 ion concentrations.
For example:
  • A neutral pH is around 7, meaning the concentrations of H鈦 and OH鈦 ions are equal.
  • In the presence of Fe虏鈦 ions, hydrolysis increases the H鈦 ion concentration, thereby decreasing the pH.
The acidic behavior of an aqueous solution like FeCl鈧 arises from the Fe虏鈦 ions' capability to undergo hydrolysis, releasing H鈦 ions. This means that even without an initial strong acid in the solution, the interaction between the ions and water can significantly influence the pH.
Understanding how pH works and what influences it is crucial for predicting the behavior of various chemical reactions in aqueous solutions.

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Most popular questions from this chapter

A white, water insoluble solid A turns yellow on heating and becomes white on cooling. A gives a clear solution B when treated with dilute \(\mathrm{HCl}\) or \(\mathrm{NaOH}\). When \(\mathrm{H}_{2} \mathrm{~S}\) is passed through solution \(\mathrm{B}\), and made neutral, a white precipitate \(\mathrm{C}\) is formed. Identify A? (a) \(\mathrm{ZnO}\) (b) \(\mathrm{CuO}\) (c) \(\mathrm{Fe}_{2} \mathrm{O}_{3}\) (d) \(\mathrm{Ag}_{2} \mathrm{O}\)

Which of the following compound is known as white vitriol? (a) \(\mathrm{ZnSO}_{4^{*}} \cdot 7 \mathrm{H}_{2} \mathrm{O}\) (b) \(\mathrm{Na}_{2} \mathrm{SO}_{4} \cdot 7 \mathrm{H}_{2} \mathrm{O}\) (c) \(\mathrm{CaCO}_{4} \cdot 2 \mathrm{H}_{2} \mathrm{O}\) (d) \(\mathrm{MgSO}_{4^{*}} 7 \mathrm{H}_{2} \mathrm{O}\)

A colourless water soluble salt \(X\) on heating gives brown gas and leaves a metallic residue. Solution of \(X\) gives brick red precipitate with solution of \(\mathrm{K}_{2} \mathrm{CrO}_{4}\). An ammonical solution of \(X\) gives a silver mirror with formic acid. Salt \(X\) is used in making indelible election ink. Identify the salt \(X\) here? (a) \(\mathrm{AgCl}\) (b) \(\mathrm{HgNO}_{3}\) (c) \(\mathrm{AgNO}_{3}\) (d) \(\mathrm{Cu}\left(\mathrm{NO}_{3}\right)_{2}\)

vSilver is a soft metal. It is hardened by alloying it wi small amounts of (a) \(\mathrm{Cu}\) (b) \(\mathrm{Fe}\) (c) \(\mathrm{Ni}\) (d) \(\mathrm{Sn}\)

Zn gives \(\mathrm{H}_{2}\) gas with \(\mathrm{H}_{2} \mathrm{SO}_{4}\) and \(\mathrm{HCl}\), but not wit \(\mathrm{HNO}_{3}\) because (a) in electrochemical series, \(\mathrm{Zn}\) is above hydrogen (b) \(\mathrm{NO}_{3}^{-}\)ion is reduced in preference to hydroniur ion (c) \(\mathrm{Zn}\) acts as an oxidizing agent when reacts wit \(\mathrm{HNO}_{3}\) (d) \(\mathrm{HNO}_{3}\) is weaker acid than \(\mathrm{H}_{2} \mathrm{SO}_{4}\) and \(\mathrm{HCl}\)

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