Chapter 17: Problem 164
A metal M readily forms water soluble sulphate \(\mathrm{MSO}_{4}\), water insoluble hydroxide \(\mathrm{M}(\mathrm{OH})_{2}\) and oxide MO which becomes inert on heating. The hydroxide is soluble in \(\mathrm{NaOH} . \mathrm{M}\) is (a) \(\mathrm{Mg}\) (b) \(\mathrm{Sr}\) (c) \(\mathrm{Be}\) (d) \(\mathrm{Ca}\)
Short Answer
Step by step solution
Analyze the Water Soluble Sulfate Property
Examine the Water Insoluble Hydroxide Property
Consider the Solubility in NaOH Property
Evaluate the Inert Oxide Property
Conclusion: Determine the Metal
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Group 2 metals
- **Properties of Group 2 Metals**: - They have two electrons in their outer shell, which they readily lose, forming +2 ions. - They display strong metallic bonds allowing them to be good conductors of electricity and heat. - Their reactivity increases as you move down the group.
- **Applications**: Group 2 metals have significant industrial importance. For instance, magnesium is used in alloys, fireworks, and incendiary devices.
Solubility
- **Solubility of Sulfates**: Generally, Group 2 metal sulfates decrease in solubility as you move down the group. Magnesium sulfate (MgSO4) is quite soluble, whereas barium sulfate (BaSO4) is almost insoluble in water.
- **Factors Affecting Solubility**: - The nature of the solvent and the temperature are key factors. - For ionic compounds, the size and charge of the ions can determine solubility. Smaller ions with higher charges usually dissolve less easily in water.
Complex ion formation
- **Role in Solubility**: When metal hydroxides such as Be(OH)2 dissolve in strong bases like NaOH, they do so by forming complex ions, like \[ \text{Be(OH)}_4^{2-}. \] These ions are more soluble, making the metal compound act differently than expected in simple water.
- **Applications**: Understanding complex ion formation is crucial in fields such as analytical chemistry and metallurgy, helping to predict and manipulate chemical behaviors and reactions.
Metal oxides
- **Properties of Group 2 Oxides**: - These oxides are generally basic and react with acids to form salts and water. - They become less reactive and more stable at higher temperatures, with some, like beryllium oxide (BeO), becoming particularly inert.
- **Uses**: Metal oxides have a wide range of applications including: - In ceramics and glass, for color and durability. - As refractory materials due to their high melting points and stability.
Beryllium chemistry
- **Unique Characteristics**: - Beryllium forms covalent bonds more readily than other Group 2 metals due to its ability to form strong directional bonds. - Its compounds, like BeO and Be(OH)2, display less ionic character.
- **Reactivity and Applications**: Although less reactive, beryllium forms useful alloys with metals like copper, enhancing their strength without significantly increasing weight. Beryllium compounds are also utilized in aerospace components, electronic devices, and as a neutron moderator in nuclear reactors.