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Which of the following is an acid? (a) \(\mathrm{P}(\mathrm{OH})_{3}\) (b) \(\mathrm{NaOH}\) (c) \(\mathrm{NH}_{4} \mathrm{OH}\) (d) \(\mathrm{Ca}(\mathrm{OH})_{2}\)

Short Answer

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(a) \(\mathrm{P} (\mathrm{OH})_{3}\) is an acid.

Step by step solution

01

Identify the Nature of Each Compound

To determine if a compound is an acid, consider its composition. Acids typically have hydrogen ions (H鈦) that they can donate when dissolved in water.
02

Analyze Each Option

Examine each given compound to see if it fits the definition of an acid.- (a) \(\mathrm{P} (\mathrm{OH})_{3}\) is phosphorous acid, which can donate H鈦 ions, thus is an acid.- (b) \(\mathrm{NaOH}\) contains hydroxide ions (OH鈦) and is a base.- (c) \(\mathrm{NH}_{4} \mathrm{OH}\) is ammonium hydroxide, a weak base.- (d) \(\mathrm{Ca}(\mathrm{OH})_{2}\) is calcium hydroxide, also a base.
03

Determine the Acid

Since acids donate H鈦 ions, the correct answer is the compound that can perform this function. Option (a) \(\mathrm{P} (\mathrm{OH})_{3}\) behaves as an acid due to its ability to release hydrogen ions.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

pH and pKa
Understanding the concepts of pH and pKa is crucial in the study of acids and bases. pH is a measure of how acidic or basic a solution is. It is calculated by the negative logarithm of the hydrogen ion concentration \([H^+]\) in a solution: \( ext{pH} = -\log[H^+]\). The pKa, on the other hand, is the measure of the strength of an acid. It is the negative logarithm of the acid dissociation constant \(K_a\): \( ext{pKa} = -\log(K_a)\).
Together, pH and pKa can help predict the behavior of an acid in a given environment. When the pH is lower than the pKa, the acid is predominantly in its protonated form. Conversely, when the pH is higher than the pKa, the acid deprotonates and forms its conjugate base. Understanding this balance is important for determining how strongly an acid will dissociate, which impacts its reactivity and its identification as either a strong or weak acid.
Acid-Base Identification
Being able to identify acids and bases is a fundamental skill in chemistry. Acids are substances that can donate a proton \(H^+\), while bases are those that can accept a proton or produce hydroxide ions \(OH^-\). This process involves observing a compound's capacity to change states.
When analyzing compounds for their acidic or basic nature, it helps to consider:
  • The presence of hydrogen ions that can be donated (in acids).
  • The presence of hydroxide ions that can be accepted (in bases).
  • Whether the compound fits into well-known categories of bases and acids; for example, many metal hydroxides are bases, like \( ext{NaOH}\) and \( ext{Ca(OH)}_2\).
  • The structure and known behavior: some compounds are notorious for acting as acids, such as \( ext{HCl}\), or as bases like \(NH_3\).
By examining these characteristics, one can determine if a substance like \(P( ext{OH})_3\) is an acid due to its ability to donate hydrogen ions, distinguishing it from bases.
Chemical Properties of Compounds
The chemical properties of compounds are determined by their structure and the types of bonds they contain. These properties affect how compounds interact in various reactions, particularly in the context of acid-base chemistry.
For example, compounds with polar covalent bonds involving hydrogen, such as \(P( ext{OH})_3\), exhibit acidic properties because they can release hydrogen ions into solution. This polar nature allows them to participate in acid-base reactions, leading to proton transfer.
In contrast, compounds like \(NaOH\) have ionic bonds and dissociate in water to produce hydroxide ions, classifying them as bases. Understanding these interactions helps when predicting
  • Reactivity: Acids and bases can react with each other to form water and salts in a neutralization reaction.
  • Solubility: Ionic compounds, such as salts, may dissolve in water to produce either acidic or basic solutions depending on the ions involved.
  • Conductivity: The ionic nature aids in electrical conductivity, a property used to identify different substances.
To effectively identify and classify substances as acids or bases, it's important to consider these chemical properties and how they influence behavior in aqueous environments.

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