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From \(\mathrm{B}_{2} \mathrm{H}_{6}\), all the following can be prepared except (a) \(\mathrm{B}_{2}\left(\mathrm{CH}_{3}\right)_{6}\) (b) \(\mathrm{NaBH}_{4}\) (c) \(\mathrm{B}_{2} \mathrm{O}_{3}\) (d) \(\mathrm{H}_{3} \mathrm{BO}_{3}\)

Short Answer

Expert verified
(d) \( \mathrm{H}_{3} \mathrm{BO}_{3} \) cannot be directly prepared from \( \mathrm{B}_{2} \mathrm{H}_{6} \).

Step by step solution

01

Identify the Role of Boron Hydride

The compound \( \mathrm{B}_{2} \mathrm{H}_{6} \) is diborane, which is a source of boron and can be used to synthesize various boron-containing compounds. Understanding its reactivity helps in knowing what types of compounds can be made from it.
02

Evaluate Option (a)

\( \mathrm{B}_{2}\left(\mathrm{CH}_{3}\right)_{6} \) is trimethylborane, which can be prepared by substituting hydride ions with methyl groups. This transformation is feasible since \( \mathrm{B}_{2} \mathrm{H}_{6} \) can engage in reactions that replace hydrogen atoms.
03

Evaluate Option (b)

\( \mathrm{NaBH}_{4} \) or sodium borohydride is a reducing agent synthesized from \( \mathrm{B}_{2} \mathrm{H}_{6} \) via reaction with sodium and hydrogen. This is a standard industrial process known for transforming diborane into sodium borohydride.
04

Evaluate Option (c)

\( \mathrm{B}_{2} \mathrm{O}_{3} \), or boron trioxide, is an oxide of boron, which can be prepared by oxidizing diborane. This process usually involves heating diborane in the presence of oxygen.
05

Evaluate Option (d)

\( \mathrm{H}_{3} \mathrm{BO}_{3} \) or boric acid is a compound that cannot be directly derived from diborane. While diborane can eventually lead to boron oxides upon oxidation, converting these oxides into \( \mathrm{H}_{3} \mathrm{BO}_{3} \) is not a direct transformation from diborane and requires an additional hydration process.
06

Determine the Exception

Based on the evaluations, option (d), \( \mathrm{H}_{3} \mathrm{BO}_{3} \), cannot be directly prepared from \( \mathrm{B}_{2} \mathrm{H}_{6} \) without multiple steps or an indirect route, unlike the other options listed.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Diborane Chemistry
Diborane (\( \mathrm{B}_{2} \mathrm{H}_{6} \)) is a fascinating and highly reactive boron hydride. It acts as a source of boron in many chemical reactions. Diborane is known for its ability to engage in a variety of chemical transformations, making it a versatile reagent in the preparation of numerous boron-containing compounds.
When dealing with diborane, it is crucial to understand its reactivity, which largely stems from the presence of its bridging hydrogen atoms. These atoms facilitate the formation of complex compounds by allowing the replacement of hydrogen units with other substituents, such as in the synthesis of trimethylborane (\( \mathrm{B}_{2}\left(\mathrm{CH}_{3}\right)_{6}\)). This ability makes diborane a cornerstone in boron chemistry, and a profound understanding of its chemical properties is essential for synthesizing various useful boron compounds.
Synthesis of Sodium Borohydride
The synthesis of sodium borohydride (\( \mathrm{NaBH}_{4} \)), a renowned reducing agent, is a process that showcases the practical application of diborane. Typically, the reaction involves diborane reacting with sodium and hydrogen under controlled conditions.
This process not only demonstrates diborane's potential as a synthetic agent but is also a staple in industrial chemistry. Sodium borohydride itself is highly valued for its reducing properties and finds a place in a variety of chemical syntheses, including the reduction of aldehydes and ketones. Understanding how diborane can be transformed into such a useful compound is a vital aspect of chemical education, illustrating the interconnectivity of chemical processes.
Boron Oxide Formation
Boron oxide, commonly referred to as boron trioxide (\( \mathrm{B}_{2} \mathrm{O}_{3} \)), can be formed by the oxidation of diborane. This tends to occur through the exposure of diborane to oxygen or by using other oxidizing agents.
The process of oxidation is generally carried out at elevated temperatures, where diborane reacts with the oxygen to yield boron oxide. The knowledge of how to form boron oxide from diborane is critical as it is a stepping stone in the production of more complex boron compounds. It highlights the role of diborane as a precursor in the formation of different boron entities through straightforward chemical processes.
Boric Acid Production
Boric Acid (\( \mathrm{H}_{3} \mathrm{BO}_{3} \)) is a compound that is not directly synthesized from diborane. Instead, its production involves further chemical transformations after the formation of boron oxide. Boron oxide obtained from oxidizing diborane can undergo hydration reactions to eventually yield boric acid.
This process usually requires the addition of water to boron trioxide. Although diborane does not directly transform into boric acid, understanding the indirect path showcases the complexity and planning required in synthetic chemistry. The synthesis route from diborane to boric acid demonstrates the need for multiple stages of chemical manipulation, emphasizing the broader principle that more complex boron compounds often arise from multi-step procedures starting with simpler precursors.

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