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Which one of the statements given below concerning properties of solutions, describe a colligative effect? (a) boiling point of pure water decreases by the addition of ethanol (b) vapour pressure of pure water decreases by the addition of nitric acid (c) vapour pressure of pure benzene decreases by the addition of naphthalene (d) boiling point of pure benzene increases by the addition of toluene

Short Answer

Expert verified
Statements (b) and (d) represent colligative effects.

Step by step solution

01

Understanding Colligative Properties

Colligative properties are properties that depend on the ratio of solute particles to solvent molecules in a solution and not on the nature of the solute itself. These properties include boiling point elevation, freezing point depression, vapor pressure lowering, and osmotic pressure.
02

Evaluating Statement (a)

Statement (a) says that the boiling point of pure water decreases with the addition of ethanol. Colligative properties like boiling point elevation imply that the boiling point should increase, not decrease, with the addition of a solute. Thus, this is not a colligative effect.
03

Evaluating Statement (b)

Statement (b) suggests that the vapor pressure of pure water decreases by adding nitric acid. This matches the colligative property of vapor pressure lowering, where the addition of a solute lowers the solvent's vapor pressure.
04

Evaluating Statement (c)

Statement (c) states that the vapor pressure of pure benzene decreases with the addition of naphthalene. This is an example of vapor pressure lowering, fitting the description of a colligative property because naphthalene is a non-volatile solute.
05

Evaluating Statement (d)

Statement (d) indicates that the boiling point of pure benzene increases with the addition of toluene. This is an example of boiling point elevation, which is a colligative property. When a non-volatile solute is added, the boiling point of the solvent increases.
06

Conclusion

There are multiple statements indicating colligative effects. Statements (b) and (d) correctly describe colligative properties: vapor pressure lowering and boiling point elevation, respectively.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Boiling Point Elevation
Boiling point elevation is one of the fascinating colligative properties of solutions. When a solute is added to a solvent – especially a non-volatile solute – the boiling point of the solvent increases. This happens because the solute particles disrupt the solvent molecules' ability to escape into the vapor phase. As more energy (in the form of heat) is required to make the solvent boil, the boiling temperature rises.

For example, when salt is added to water, it causes the water's boiling point to rise. This is why adding salt to cooking pasta is a classic kitchen trick to slightly increase the cooking temperature. Understanding boiling point elevation helps in various fields, from cooking improvements to antifreeze production for car engines, where solutions prevent freezing in wintery conditions.
  • Increases solvent's boiling point.
  • Heightened boiling point due to solute particles.
  • More heat required to boil the solution.
Vapor Pressure Lowering
Vapor pressure lowering is another key colligative property. In a pure solvent, molecules readily escape into the vapor above the liquid, establishing a certain vapor pressure. However, when a non-volatile solute, like sugar or salt, is added to a solvent, the vapor pressure of the solvent decreases.

The solute particles take up space and reduce the number of solvent molecules that can escape into the vapor phase. This decrease in vapor pressure is crucial for understanding weather phenomena, as well as the behavior of aerosols and chemical processes in both industrial and natural settings.
  • Solute reduces solvent's escaping molecules.
  • Leads to lowered vapor pressure.
  • Crucial for varied real-world applications.
Solutions
Solutions are homogeneous mixtures composed of two or more substances. The core components of any solution include a solute, which is the substance being dissolved, and the solvent, which is the substance that dissolves the solute. In everyday examples, water often acts as the solvent, dissolving solutes such as sugar or salt.

Solutions have unique properties that are neither characteristic of the pure solute nor the pure solvent. Properties that depend on the number of solute particles in a given amount of solvent are considered colligative properties. These include:
  • Boiling point elevation.
  • Freezing point depression.
  • Vapor pressure lowering.
  • Osmotic pressure.
Understanding solutions and the concept of colligative properties enhances our comprehension of chemical reactions and processes, leading to better industrial applications and more accurate scientific predictions.

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Most popular questions from this chapter

Which one of the following statements is false? (a) two sucrose solutions of same molality prepared in different solvents will have the same freezing point depression (b) the osmotic pressure ( \(\pi\) ) of a solution is given by the equation \(\pi=\mathrm{MRT}\), where \(\mathrm{M}\) is the molarity of the solution (c) Raoult's law states that the vapour pressure of a component over a solution is proportional to its mole fraction (d) the correct order of osmotic pressure for \(0.01 \mathrm{M}\) aqueous solution of each compound is \(\mathrm{BaCl}_{2}>\) \(\mathrm{KCl}<\mathrm{CH}_{3} \mathrm{COOH}>\) Sucrose

Equal volumes of \(0.1 \mathrm{M} \mathrm{AgNO}_{3}\) and \(0.2 \mathrm{M} \mathrm{NaCl}\) are mixed. The concentration of nitrate ions in the mixture will be (a) \(0.1 \mathrm{M}\) (b) \(0.05 \mathrm{M}\) (c) \(0.2 \mathrm{M}\) (d) \(0.15 \mathrm{M}\)

Which of the following salt will have the same volume of vant Hoff factor 'i'as that of \(\left.\mathrm{K}_{4}[\mathrm{Fe}(\mathrm{CN})]\right\\}\) (a) \(\mathrm{Al}_{2}\left(\mathrm{SO}_{4}\right)_{3}\) (b) \(\mathrm{NaCl}\) (c) \(\mathrm{Al}\left(\mathrm{NO}_{3}\right)_{3}\) (d) \(\mathrm{Na}_{2} \mathrm{SO}_{4}\)

Which of the following \(0.1 \mathrm{M}\) aqueous solutions will have the lowest freezing point? (a) \(\mathrm{K}_{2} \mathrm{SO}_{4}\) (b) \(\mathrm{NaCl}\) (c) urea (d) glucose

Which of the following can form minimum boiling point azeotropic mixture? (a) Ethyl alcohol + water (b) Carbon tetrachloride \(+\) chloroform (c) Ethyl alcohol + water (d) Acetone \(+\) chloroform

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