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A mixture of two salts is not water soluble but dissolves completely in dil. HCl to form a colourless solution. The mixture could be (a) \(\mathrm{BaCO}_{3}\) and \(\mathrm{ZnS}\) (b) \(\mathrm{AgNO}_{3}\) and \(\mathrm{KBr}\) (c) \(\mathrm{Mn}\left(\mathrm{NO}_{3}\right)_{2}\) and \(\mathrm{MgSO}_{4}\) (d) \(\mathrm{FeCl}_{3}\) and \(\mathrm{CaCO}_{3}\)

Short Answer

Expert verified
The mixture could be (a) BaCO₃ and ZnS.

Step by step solution

01

Understanding Solubility in Dilute HCl

To solve this problem, we must determine which combination of salts forms a colorless solution when dissolved in dilute hydrochloric acid. Since the solution becomes clear, the salts must react with dilute HCl to form soluble products.
02

Analyzing Reaction with HCl for Each Option

(a) **BaCO₃ and ZnS:** BaCO₃ reacts with HCl to form soluble BaCl₂ and CO₂ gas. ZnS reacts with HCl to form ZnCl₂ and H₂S gas. (b) **AgNO₃ and KBr:** AgNO₃ is soluble in water and HNO₃, and does not react with HCl. KBr dissolves in water and does not react with HCl to form a gas. (c) **Mn(NO₃)₂ and MgSO₄:** Both are soluble in water and do not react with HCl to form gases. (d) **FeCl₃ and CaCO₃:** CaCO₃ reacts with HCl forming soluble CaCl₂ and CO₂ gas. FeCl₃ is already soluble in water.
03

Identifying Colorless Solution Formation

From the prior analysis, options (a) and (d) result in reaction with HCl forming soluble chlorides and releasing gases (COâ‚‚ and Hâ‚‚S for a, COâ‚‚ for d) which could be overlooked as solutions turn colorless. Neither b nor c incorporates salts that dissolve completely or release gas upon interaction with HCl to form a colorless solution.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Reactions
In chemistry, reactions occur when substances interact to form new products. These interactions follow specific rules and can be categorized into different types. One of them is the exchange of ions between substances, often referred to as a double replacement reaction. This kind of reaction plays a significant role when dealing with solubility and is exhibited when salts dissolve or do not dissolve in solutions, such as with hydrochloric acid (HCl).
For example, when barium carbonate (\( \text{BaCO}_3 \)) is treated with dilute hydrochloric acid, a chemical reaction occurs where (\( \text{BaCO}_3 \)) and HCl exchange ions to form soluble barium chloride (\( \text{BaCl}_2 \)) and carbon dioxide gas (\( \text{CO}_2 \)). This reaction represents a typical case where an insoluble substance becomes soluble through a chemical transformation.
  • Reactions involve breaking and forming new bonds.
  • The reaction between acids and bases, or salts, often involves the release of gases like (\( \text{CO}_2 \)) or (\( \text{H}_2\)).
  • Products formed are often different from the initial reactants in their solubility and physical state.
Acid-Base Reactions
Acid-base reactions are a fundamental part of chemistry where acids and bases react to form salts and water. These reactions are also crucial for understanding the solubility or insolubility of certain chemical compounds in solutions.
When an acid like hydrochloric acid (\( \text{HCl} \)) is added to a base-containing compound or a carbonate compound, a gas is often released, and a soluble salt is formed. For instance, with calcium carbonate (\( \text{CaCO}_3 \)), when reacted with HCl, the end products are calcium chloride (\( \text{CaCl}_2 \)), carbon dioxide (\( \text{CO}_2 \)) gas, and water.
  • Acid-base reactions are typically characterized by the production of water and a salt, some releasing gases.
  • Such reactions can make insoluble salts dissolve by forming soluble chlorides.
  • The reaction's outcome often depends on the balance between acid strength and the chemical nature of the base involved.
Chemical Compounds
Chemical compounds are substances made up of two or more different types of atoms bonded together. These compounds can be broadly classified based on their chemical characteristics and reactions. For example, in the context of solubility, salts are often discussed.
Salts like barium carbonate (\( \text{BaCO}_3 \)) and zinc sulfide (\( \text{ZnS} \)) highlight how different compounds interact with acids. BaCOencompasses a carbon-oxygen bond susceptible to hydrochloric acid, releasing (\( \text{CO}_2 \)) gas upon reaction. Meanwhile, (\( \text{ZnS} \)), when interacting with HCl, results in the release of hydrogen sulfide (\( \text{H}_2\text{S} \)) gas and the formation of soluble zinc chloride (\( \text{ZnCl}_2 \)).
  • Compounds exhibit distinctive properties - solubility being a key one.
  • Interactions with acids can transform insoluble compounds through chemical reactions.
  • Studying compounds reveals reactive potential and properties under various conditions.
Solution Formation
Solution formation is a process where solutes dissolve in solvents, creating homogeneous mixtures. The solubility of compounds depends on factors such as temperature and chemical nature of the solute and solvent.
Particularly in acid solutions, certain salts that are not otherwise soluble can become dissolved. For instance, a mixture that is insoluble in water can dissolve in hydrochloric acid when reactions result in the formation of new, soluble substances.
  • Solutions are categorized mainly as aqueous when a substance dissolves in water or acidic solution if dissolved in an acid.
  • The nature of molecules involved determines whether a solution becomes colorless or stays colored.
  • Observing a clear solution indicates successful solubility where initial substances may have reacted completely.
Understanding these dynamics helps in predicting how different salt mixtures behave in varying environments.

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Most popular questions from this chapter

Amount of oxalic acid present in a solution can be determined by its titration with \(\mathrm{KMnO}_{4}\) solution in the presence of \(\mathrm{H}_{2} \mathrm{SO}_{4} .\) The titration gives unsatisfactory result when carried out in the presence of \(\mathrm{HCl}\), because of (a) Gets oxidized by oxalic acid to chlorine (b) Furnishes \(\mathrm{H}^{+}\)ions in addition to those from oxalic acid (c) Reduces permanganate to \(\mathrm{Mn}^{2+}\) (d) Oxidises oxalic acid to carbon dioxide and water

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