Chapter 34: Problem 81
A mixture of two salts is not water soluble but dissolves completely in dil. HCl to form a colourless solution. The mixture could be (a) \(\mathrm{BaCO}_{3}\) and \(\mathrm{ZnS}\) (b) \(\mathrm{AgNO}_{3}\) and \(\mathrm{KBr}\) (c) \(\mathrm{Mn}\left(\mathrm{NO}_{3}\right)_{2}\) and \(\mathrm{MgSO}_{4}\) (d) \(\mathrm{FeCl}_{3}\) and \(\mathrm{CaCO}_{3}\)
Short Answer
Step by step solution
Understanding Solubility in Dilute HCl
Analyzing Reaction with HCl for Each Option
Identifying Colorless Solution Formation
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chemical Reactions
For example, when barium carbonate (\( \text{BaCO}_3 \)) is treated with dilute hydrochloric acid, a chemical reaction occurs where (\( \text{BaCO}_3 \)) and HCl exchange ions to form soluble barium chloride (\( \text{BaCl}_2 \)) and carbon dioxide gas (\( \text{CO}_2 \)). This reaction represents a typical case where an insoluble substance becomes soluble through a chemical transformation.
- Reactions involve breaking and forming new bonds.
- The reaction between acids and bases, or salts, often involves the release of gases like (\( \text{CO}_2 \)) or (\( \text{H}_2\)).
- Products formed are often different from the initial reactants in their solubility and physical state.
Acid-Base Reactions
When an acid like hydrochloric acid (\( \text{HCl} \)) is added to a base-containing compound or a carbonate compound, a gas is often released, and a soluble salt is formed. For instance, with calcium carbonate (\( \text{CaCO}_3 \)), when reacted with HCl, the end products are calcium chloride (\( \text{CaCl}_2 \)), carbon dioxide (\( \text{CO}_2 \)) gas, and water.
- Acid-base reactions are typically characterized by the production of water and a salt, some releasing gases.
- Such reactions can make insoluble salts dissolve by forming soluble chlorides.
- The reaction's outcome often depends on the balance between acid strength and the chemical nature of the base involved.
Chemical Compounds
Salts like barium carbonate (\( \text{BaCO}_3 \)) and zinc sulfide (\( \text{ZnS} \)) highlight how different compounds interact with acids. BaCOencompasses a carbon-oxygen bond susceptible to hydrochloric acid, releasing (\( \text{CO}_2 \)) gas upon reaction. Meanwhile, (\( \text{ZnS} \)), when interacting with HCl, results in the release of hydrogen sulfide (\( \text{H}_2\text{S} \)) gas and the formation of soluble zinc chloride (\( \text{ZnCl}_2 \)).
- Compounds exhibit distinctive properties - solubility being a key one.
- Interactions with acids can transform insoluble compounds through chemical reactions.
- Studying compounds reveals reactive potential and properties under various conditions.
Solution Formation
Particularly in acid solutions, certain salts that are not otherwise soluble can become dissolved. For instance, a mixture that is insoluble in water can dissolve in hydrochloric acid when reactions result in the formation of new, soluble substances.
- Solutions are categorized mainly as aqueous when a substance dissolves in water or acidic solution if dissolved in an acid.
- The nature of molecules involved determines whether a solution becomes colorless or stays colored.
- Observing a clear solution indicates successful solubility where initial substances may have reacted completely.