Chapter 30: Problem 116
Which of the following is a polyamide? [2005] (a) Teflon (b) Nylon-6, 6 (c) Terylene (d) Bakelite
Short Answer
Expert verified
Nylon-6, 6 is a polyamide.
Step by step solution
01
Understanding Polyamides
Polyamides are polymers where the repeating units are linked by amide bonds. To identify which option is a polyamide, we need to look for a polymer made by reacting compounds with amide (–CONH–) linkages.
02
Identify the Structure of Each Option
Let's start by identifying what each option is made of:
(a) Teflon - Made of tetrafluoroethylene, it is not a polyamide but a polyfluorinated polymer.
(b) Nylon-6, 6 - Formed by condensation polymerization of hexamethylenediamine and adipic acid, forming amide linkages.
(c) Terylene - A polyester formed from ethylene glycol and terephthalic acid, not an amide.
(d) Bakelite - Made by polymerization of phenol and formaldehyde, it is a phenolic resin, not a polyamide.
03
Analyzing the Options for Amide Linkages
From the above analysis:
Teflon and Terylene are excluded for being a polyfluorinated compound and a polyester respectively, which don't use amide linkages.
Bakelite is a phenolic resin and also doesn't have amide linkages.
Nylon-6, 6, however, is made through reactions that form amide linkages.
04
Reaffirm the Characteristics of Polyamides
Polyamides are generally characterized by the presence of recurring amide bonds in their structure. Nylon-6, 6, specifically, is named for these linkages and is well-known for them.
05
Select the Correct Option
With the understanding that Nylon-6, 6 has the necessary amide linkages indicative of a polyamide, we conclude it must be the correct answer.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Nylon-6, 6
Nylon-6, 6 is a type of synthetic polymer known as a polyamide, which is a crucial material in various applications due to its robust properties. Its name comes from the two monomers it is synthesized from:
- Hexamethylenediamine
- Adipic acid
- High tensile strength
- Good elasticity
- Excellent resistance to abrasion
Amide Linkages
Amide linkages are the bonds that join the monomers in polyamides, such as Nylon-6, 6. They form through a chemical reaction between a carboxylic acid group (\[-COOH\]) and an amine group (\[-NH_2\]). During this reaction, water (\[H_2O\]) is released as a byproduct. Known as an amide bond or peptide bond, this linkage is denoted by the structure:
\[-CONH-\] This bond is crucial to the structure and properties of polyamides. Amide linkages provide strength and stability to the polymer chains, making materials like Nylon-6, 6 tough and durable.
\[-CONH-\] This bond is crucial to the structure and properties of polyamides. Amide linkages provide strength and stability to the polymer chains, making materials like Nylon-6, 6 tough and durable.
- Robust bond holding the polymer chain together
- Creates a repeating pattern in the polymer
- Contributes to high melting point and strength
Polymerization
Polymerization is a chemical process that combines small molecules called monomers into a larger compound known as a polymer. In the case of Nylon-6, 6, this process is specifically known as condensation polymerization.
During this process, monomers with carboxylic acid and amine groups react together, releasing a small molecule, usually water, each time a bond forms. For Nylon-6, 6, this means each time an amide linkage is formed, a water molecule is expelled.
Some traits of polymers like Nylon-6, 6 that result from polymerization include:
During this process, monomers with carboxylic acid and amine groups react together, releasing a small molecule, usually water, each time a bond forms. For Nylon-6, 6, this means each time an amide linkage is formed, a water molecule is expelled.
Some traits of polymers like Nylon-6, 6 that result from polymerization include:
- High thermal stability
- Flexibility in application
- Ability to be formed into fibers