Chapter 16: Problem 9
In the reaction \(\mathrm{B}_{2} \mathrm{H}_{6}+2 \mathrm{KOH}+2 \mathrm{X} \longrightarrow 2 \mathrm{Y}+6 \mathrm{H}_{2}\) \(X\) and \(Y\) are respectively (a) \(\mathrm{HCl}, \mathrm{KBO}_{3}\) (b) \(\mathrm{H}_{2}, \mathrm{H}_{3} \mathrm{BO}_{3}\) (c) \(\mathrm{H}_{2} \mathrm{O}, \mathrm{KBO}_{2}\) (d) \(\mathrm{H}_{2} \mathrm{O}, \mathrm{KBO}_{3}\)
Short Answer
Step by step solution
Identify the reactants and products
Understand the role of the reactants
Analyzing the options for \( \mathrm{X} \)
Analyzing the options for \( \mathrm{Y} \)
Conclusion
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chemical Equation Balancing
- Write down the number of atoms of each element in the reactants and the products.
- Compare these numbers and add coefficients to the chemical formulas to balance the atoms.
- Always start by balancing elements that appear in only one reactant and one product first.
- Continue adjusting coefficients systematically until all elements are balanced.
- Check your work to ensure that the coefficients are in the simplest possible ratio.
Oxidation States
- Elements in their natural state have an oxidation number of zero. For example, \(\mathrm{O}_2\) or \(\mathrm{H}_2\).
- The oxidation state of a simple ion is equal to its charge. For example, \(\mathrm{Na}^+\) has an oxidation state of +1.
- In compounds, hydrogen usually has an oxidation state of +1, and oxygen usually has an oxidation state of -2.
- Sum of oxidation states for all atoms in a neutral compound must be zero.
Metaborate Formation
- Boranes interact with bases through hydrolysis reactions where water molecules play a key role.
- During this process, hydrogen atoms from borane are typically displaced, leading to the release of hydrogen gas.
- As a part of the rearrangement, the boron atom forms bonds with oxygen, producing anionic species like \(\mathrm{BO}_2^-\).