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Which of the following is reduced by hydrogen peroxide in acidic medium? (a) ferrous sulphate (b) potassium iodide (c) potassium ferrocyanide (d) potassium permanganate

Short Answer

Expert verified
Potassium permanganate (d) is reduced by hydrogen peroxide in acidic medium.

Step by step solution

01

Identifying Reducing Capabilities of Hydrogen Peroxide

In an acidic medium, hydrogen peroxide (H鈧侽鈧) can act as an oxidizing agent, converting substances to their reduced forms. Thus, we need to identify which compound can be oxidized by H鈧侽鈧 in a chemical reaction.
02

Evaluating each Option

- **Option (a): Ferrous sulphate (FeSO鈧)** - Converts Fe虏鈦 to Fe鲁鈦, hence it is oxidized, not reduced. - **Option (b): Potassium iodide (KI)** - KI can be oxidized to iodine (I鈧), where iodide ions (I鈦) are oxidized. - **Option (c): Potassium ferrocyanide (K鈧刐Fe(CN)鈧哴)** - Remains as ferrocyanide, not typically oxidized by H鈧侽鈧 in acidic medium. - **Option (d): Potassium permanganate (KMnO鈧)** - MnO鈧勨伝 ions get reduced to Mn虏鈦 in acidic medium.
03

Focusing on Potassium Permanganate

Potassium permanganate (KMnO鈧) undergoes reduction by hydrogen peroxide in acidic medium as follows: \[ 2 MnO_4^- + 5 H_2O_2 + 6 H^+ \rightarrow 2 Mn^{2+} + 5 O_2 + 8 H_2O \]In this reaction, the MnO鈧勨伝 ions are reduced to Mn虏鈦.
04

Confirming the Reducing Substance

After analyzing the options, it's clear that hydrogen peroxide reduces potassium permanganate in an acidic medium, as observed from the balanced reaction equation provided in Step 3.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Oxidizing Agent
Hydrogen peroxide (H鈧侽鈧) serves as a versatile chemical in oxidation reactions, especially in acidic environments. As an oxidizing agent, it has the capacity to accept electrons from other substances during a chemical reaction. This acceptance results in the oxidation of the other substance while hydrogen peroxide undergoes reduction itself. The effectiveness of H鈧侽鈧 as an oxidizing agent is evident in various reactions.
For instance, consider its role when interacting with potassium permanganate in acidic medium. Here:
  • Potassium permanganate (KMnO鈧) is known to be reduced, indicating H鈧侽鈧's strong oxidizing ability.
  • This interaction leads to the reduction of MnO鈧勨伝 ions to Mn虏鈦 ions.
These processes highlight the dual nature of H鈧侽鈧, showcasing its role as a reducer and oxidizer in different scenarios.
In summary, hydrogen peroxide's features as an oxidizing agent make it a valuable tool in chemical reactions, promoting changes where other corresponding substances alter their oxidation states.
Reduction Reactions
Reduction reactions involve the gaining of electrons by a molecule, atom, or ion. This electron gain results in a decrease in the oxidation state of the substance being reduced. A classic example in chemistry is the reduction of potassium permanganate (KMnO鈧) using hydrogen peroxide in acidic conditions. During this reaction:
  • The manganese in the permanganate ion gains electrons and is reduced from a +7 oxidation state in MnO鈧勨伝 to a +2 oxidation state in Mn虏鈦.
  • This reduction exemplifies the electron acceptance characteristic of these reactions.
Reduction is almost always paired with an oxidation reaction, where another species gives up electrons, thereby complementing the whole redox process.
Understanding reduction helps in predicting product formation and balancing chemical equations. By recognizing these electron shifts, students can better predict reaction outcomes and the roles of different agents in a chemical scenario.
Chemical Reactions in Acidic Medium
Chemical reactions often behave differently depending on the medium they occur in, with acidic mediums providing unique reaction pathways. In an acidic environment, reactions generally involve plenty of H鈦 ions, influencing the overall course of the reaction.
When hydrogen peroxide reacts with potassium permanganate (KMnO鈧) in acidic medium as shown by the equation: \[2 MnO_4^- + 5 H_2O_2 + 6 H^+ \rightarrow 2 Mn^{2+} + 5 O_2 + 8 H_2O\] The presence of H鈦 ions helps drive the reduction process of MnO鈧勨伝. This reaction is an excellent example of how conditions such as pH can significantly alter chemical pathways.
  • Acidic conditions often favor oxidation-reduction reactions due to the abundance of protons.
  • They help stabilize certain ions, driving chemical transformations that might not occur otherwise.
Reactions in acidic media are crucial in both laboratory settings and in industrial applications, where controlled environments dictate how efficiently reactions proceed.

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Most popular questions from this chapter

Nitrogen (I) oxide is produced by 1\. thermal decomposition of ammonium nitrate 2\. disproportionation of \(\mathrm{N}_{2} \mathrm{O}_{4}\) 3\. thermal decomposition of ammonium nitrite 4\. interaction of hydroxyl amine and nitrous acid (a) 1,2 (b) 2,3 (c) 1,4 (d) 2,4

Which of the following statements are correct? (1) Temporary hardness of water is due to the presence of bicarbonates of calcium and magnesium in it (2) Permutit is artificial zeolite (3) \(\mathrm{H}_{2} \mathrm{O}_{2}\) acts as an oxidizing agent in the following reaction $$ \mathrm{Cl}_{2}+\mathrm{H}_{2} \mathrm{O}_{2} \longrightarrow \mathrm{O}_{2}+2 \mathrm{HCl} $$ (4) \(\mathrm{H}_{2} \mathrm{O}_{2}\) is used a bleaching agent for delicate textiles. (a) 1,2 and 3 (b) 1,2 and 4 (c) 2,3 and 4 (d) 1,3 and 4

Which of the following statement (s) is /are correct? (a) Ammonia is oxidized to \(\mathrm{NO}_{2}\) by oxygen at \(800^{\circ} \mathrm{C}\) in presence of a catalyst platinum (b) Nitric acid on standing slowly turns yellow. (c) Colloidal sulphur is formed when \(\mathrm{H}_{2} \mathrm{~S}\) gas is passed through nitric acid solution (d) \(\mathrm{N}_{2} \mathrm{O}_{3}\) gas dissolves in water giving a pale blue solution.

\(\mathrm{NH}_{3}\) cannot be obtained by (a) heating of \(\mathrm{NH}_{4} \mathrm{NO}_{3}\) or \(\mathrm{NH}_{4} \mathrm{NO}_{2}\) (b) heating of \(\mathrm{NH}_{4} \mathrm{Cl}\) or \(\left(\mathrm{NH}_{4}\right)_{2} \mathrm{CO}_{3}\) (c) heating of \(\mathrm{NH}_{4} \mathrm{NO}_{3}\) with \(\mathrm{NaOH}\) (d) reaction of AIN or \(\mathrm{Mg}_{3} \mathrm{~N}_{2}\) or \(\mathrm{CaCN}_{2}\) with \(\mathrm{H}_{2} \mathrm{O}\)

In context with the industrial preparation of hydrogen from water gas \(\left(\mathrm{CO}+\mathrm{H}_{2}\right)\), which of the following is the correct statement? (a) \(\mathrm{CO}\) and \(\mathrm{H}_{2}\) are fractionally separated using differences in their densities (b) \(\mathrm{CO}\) is removed by absorption in aqueous \(\mathrm{Cu}_{2} \mathrm{Cl}_{2}\) solution (c) \(\mathrm{H}_{2}\) is removed through occlusion with \(\mathrm{Pd}\) (d) \(\mathrm{CO}\) is oxidized to \(\mathrm{CO}_{2}\) with steam in the presence of a catalyst followed by absorption of \(\mathrm{CO}_{2}\) in alkali.

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