Chapter 14: Problem 132
Which of the following will displace the halogen from the solution of the halide? (a) \(\mathrm{Cl}_{2}\) added to a KBr solution (b) \(\mathrm{Br}_{2}\) added to an \(\mathrm{NaCl}\) solution (c) \(\mathrm{Br}\), added to a KI solution (d) \(\mathrm{Cl}_{2}^{2}\) added to an \(\mathrm{NaF}\) solution
Short Answer
Step by step solution
Understand Halogen Reactivity
Assess Each Reaction Possibility
Conclusion
Unlock Step-by-Step Solutions & Ace Your Exams!
-
Full Textbook Solutions
Get detailed explanations and key concepts
-
Unlimited Al creation
Al flashcards, explanations, exams and more...
-
Ads-free access
To over 500 millions flashcards
-
Money-back guarantee
We refund you if you fail your exam.
Over 30 million students worldwide already upgrade their learning with 91Ó°ÊÓ!
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Halogen Reactivity
\[ \text{Fluorine (F)} > \text{Chlorine (Cl)} > \text{Bromine (Br)} > \text{Iodine (I)} \]
This implies that fluorine is the most reactive halogen, capable of displacing any other halide ion in a compound. Chlorine follows, able to displace bromine and iodine, but not fluorine. Similarly, bromine can displace iodine but is less reactive than chlorine and fluorine.
Displacement Reactions
- Chlorine gas added to potassium bromide will displace bromine, forming potassium chloride and bromine gas.
- Bromine, being less reactive than chlorine, will not displace chlorine from sodium chloride.
Periodic Table Trends
- Increasing atomic size: Atoms grow larger as additional electron shells are added.
- Decreasing ionization energy: It becomes easier for the outer electrons to be removed.
- Decreasing electronegativity: The ability of an atom to attract electrons diminishes.
Reactivity Series
- A more reactive halogen can displace a less reactive halide from a solution.
- This concept is crucial in predicting outcomes of displacement reactions.
Chemical Reactions in Aqueous Solutions
- Halogens dissolve in water to react with halide solutions based on their reactivity.
- Displacement occurs when halogens in solutions react with halide ions to form new compounds.