Chapter 13: Problem 89
Among the following compounds which contain all 3 type of bonds (i) \(\mathrm{NH}_{4} \mathrm{Cl}\) (ii) \(\mathrm{K}_{3} \mathrm{Fe}(\mathrm{CN})_{6}\) (iii) \(\mathrm{H}_{2} \mathrm{O}_{2}\) (iv) \(\mathrm{H}_{2} \mathrm{SO}_{4}\) (v) \(\mathrm{CaCO}_{3}\) (a) I, II (b) I, II, V (c) I, II, IV (d) I, II, III
Short Answer
Step by step solution
Identify the types of bonds
Analyze NH4Cl
Analyze K3Fe(CN)6
Analyze H2O2
Determine if H2SO4 has all bond types
Analyze CaCO3
Conclusion
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Ionic Bonds
These ions with opposite charges attract each other, creating a strong bond.Ionic bonds typically occur between metals and non-metals. Metals, like sodium or potassium, lose electrons to form positively charged ions, while non-metals, like chlorine, gain electrons to form negatively charged ions. This attraction results in compounds like sodium chloride (NaCl).Key features of ionic bonds include:
- High melting and boiling points due to strong attractions.
- Electrical conductivity when dissolved in water or melted.
Similarly, in \( ext{CaCO}_3\), it's between \( ext{Ca}^{2+}\) and \( ext{CO}_3^{2-}\).
Covalent Bonds
This type of bond usually occurs between non-metal atoms with similar electronegativities.The shared electrons allow each atom to achieve the electron configuration of a noble gas, resulting in a stable bond.
Molecules like water (Hâ‚‚O) and carbon dioxide (COâ‚‚) are formed by covalent bonds.Key characteristics of covalent bonds include:
- Typically lower melting and boiling points than ionic compounds.
- Generally poor conductors of electricity.
In \( ext{K}_3 ext{Fe}( ext{CN})_6\), they appear between carbon and nitrogen in \( ext{CN}^-\), while in \( ext{CaCO}_3\), they occur between carbon and oxygen within \( ext{CO}_3^{2-}\).
Coordinate Bonds
This bond resembles a regular covalent bond in strength and characteristics.Coordinate bonds are common in complex ions and molecules where one atom has a lone pair of electrons.
These lone pairs are used to form bonds with electron-deficient atoms or ions.Unique points about coordinate bonds include:
- They often involve transition metals and ligands in complex ion formation.
- The resulting bonds contribute to the overall stability and characteristics of the compound.
In \( ext{K}_3 ext{Fe}( ext{CN})_6\), each \( ext{CN}^-\) donates electron pairs to \( ext{Fe}^{3+}\), establishing strong coordinate bonds that stabilize the complex.