Chapter 9: Problem 38
Laws of electrolysis was given by (a) Faraday (b) Ostwald (c) Arrhenius (d) Lamark
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Chapter 9: Problem 38
Laws of electrolysis was given by (a) Faraday (b) Ostwald (c) Arrhenius (d) Lamark
These are the key concepts you need to understand to accurately answer the question.
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The standard reduction potentials of \(\mathrm{Ag}, \mathrm{Cu}, \mathrm{Co}\) and \(\mathrm{Zn}\) are \(0.799,0.337,-0.277\) and \(-0.762 \mathrm{~V}\) respectively. Which of the following cells will have maximum cell emf? (a) \(\mathrm{Zn}\left|\mathrm{Zn}^{2+}(\mathrm{IM}) \| \mathrm{Cu}^{2+}(1 \mathrm{M})\right| \mathrm{Cu}\) (b) \(\mathrm{Zn}\left|\mathrm{Zn}^{2+}(\mathrm{IM}) \| \mathrm{Ag}^{+}(\mathrm{lM})\right| \mathrm{Ag}\) (c) \(\mathrm{Cu}\left|\mathrm{Cu}^{2+}(\mathrm{IM}) \| \mathrm{Ag}^{+}(\mathrm{IM})\right| \mathrm{Ag}\) (d) \(\mathrm{Zn}\left|\mathrm{Zn}^{2+}(\mathrm{IM}) \| \mathrm{Co}^{2+}(\mathrm{IM})\right| \mathrm{Co}\)
The standard reduction potentials of \(\mathrm{Zn}^{2} \mid \mathrm{Zn}\) and \(\mathrm{Cu}^{2}\) \(\mid \mathrm{Cu}\) are \(-0.76 \mathrm{~V}\) and \(+0.34 \mathrm{~V}\) respectively. What is the cell emf (in V) of the following cell? \((\mathrm{RT} / F=0.059)\) \(\mathrm{Zn}\left|\mathrm{Zn}^{2}(0.05 \mathrm{M}) \| \mathrm{Cu}^{21}(0.005 \mathrm{M})\right| \mathrm{Cu}\) (a) \(1.1295\) (b) \(1.0705\) (c) \(1.1\) (d) \(1.041\)
If \(E^{\circ}\left(\mathrm{Fe}^{2+} / \mathrm{Fe}\right)=-0.441 \mathrm{~V}\) and \(E^{\circ}\left(\mathrm{Fe}^{3+} / \mathrm{Fe}^{2 t}\right)=0.771 \mathrm{~V}\) the standard emf of the reaction \(\mathrm{Fe}+2 \mathrm{Fe}^{3+} \longrightarrow 3 \mathrm{Fe}^{2+}\) will be (a) \(1.212 \mathrm{~V}\) (b) \(0.111 \mathrm{~V}\) (c) \(0.330 \mathrm{~V}\) (d) \(1.653 \mathrm{~V}\)
For the redox reaction \(\mathrm{MnO}_{4}^{-}+\mathrm{C}_{2} \mathrm{O}_{4}^{2-}+\mathrm{H}^{+} \longrightarrow \mathrm{Mn}^{2+}+\mathrm{CO}_{2}+\mathrm{H}_{2} \mathrm{O}\), the correct coefficients of the reactants for the balanced reaction are (a) (b) (c) \(\begin{array}{clc}\mathrm{MnO}_{4}^{-} & \mathrm{C}_{2} \mathrm{O}_{4}^{2-} & \mathrm{H}^{+} \\ 2 & 5 & 16 \\ 16 & 5 & 2 \\ 5 & 16 & 2 \\ 2 & 16 & 5\end{array}\) (d)
Removal to basic oxide from metal before electroplating is known as (a) poling (b) galvanizing (c) pickling (d) anodizing
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