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One litre of \(1 \mathrm{M} \mathrm{CuSO}_{4}\) solution is electrolysed. After passing \(2 \mathrm{~F}\) of electricity, molarity of \(\mathrm{CuSO}_{4}\) solution will be (a) \(\mathrm{M} / 2\) (b) \(\mathrm{M} / 4\) (c) \(\mathrm{M}\) (d) 0

Short Answer

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(d) 0

Step by step solution

01

Understand Electrolysis

Electrolysis is the process of driving a non-spontaneous reaction using electrical energy. In this case, the reaction happening is the reduction of copper ions (Cu虏鈦) to copper metal at the cathode.
02

Initial Molarity Calculation

Initially, 1 litre of solution contains 1 mole of CuSO鈧 because the concentration is 1 mol/L.
03

Calculate Moles of Electrons Transferred

Faraday's first law of electrolysis states that the mass of substance deposited or liberated at an electrode is proportional to the number of moles of electrons passed through the electrolyte. Since 2 Faradays of electricity are used, this implies 2 moles of electrons are passed.
04

Copper Deposition Process

Cu虏鈦 ions in the solution gain 2 electrons (from the electrical energy) to form copper metal. Thus, Cu虏鈦 + 2e鈦 鈫 Cu掳. The reaction consumes 1 mole of Cu虏鈦 ions for every 2 moles of electrons.
05

Determine Moles of Cu虏鈦 Remaining

Because 2 moles of electrons were used, 1 mole of Cu虏鈦 ions is deposited as copper metal. This results in the complete consumption of the initial Cu虏鈦 ions in the solution (since we started with 1 mole of Cu虏鈦).
06

Final Molarity Calculation

Since all the Cu虏鈦 ions are deposited as metal, no Cu虏鈦 ions remain in the solution. Thus, the molarity of CuSO鈧 reduces to 0.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Faraday's Laws of Electrolysis
Faraday's Laws of Electrolysis are fundamental principles used to understand the relationship between electric charge and chemical reactions in electrolysis. Faraday's first law states that the amount of substance deposited at an electrode is directly proportional to the amount of electric charge passed through the electrolyte. This means that if you double the electric charge, the amount of substance deposited will also double.

Faraday's second law dives deeper and tells us that when the same quantity of electricity is passed through electrolytes, the masses of substances deposited are in the ratio of their chemical equivalent weights. The chemical equivalent weight is calculated by dividing a substance's molar mass by its valency.
  • **Practical Implication**: These laws are useful in predicting how much of a substance will be deposited or dissolved during electrolysis when a specific amount of electricity is used.
  • **For our exercise**: Knowing that 2 Faradays of electricity corresponds to 2 moles of electrons helps us conclude that 1 mole of Cu鈦郝 is deposited since 2 electrons are required per copper ion.
Copper(I) sulfate (CuSO4) solution
Copper(I) sulfate, \CuSO_4, is an important chemical used in various applications, including electrolysis processes. In its aqueous form, it dissociates into \(\text{Cu}^{2+}\) ions and SO鈧劼测伝 ions. The solution's behavior under electrolysis is crucial in extracting or plating the copper ions on electrodes. This is because the \(\text{Cu}^{2+}\) ions in the solution act as the source of copper that will be deposited at the cathode when electricity is applied.

When you have a 1 M solution of CuSO鈧, it means there is 1 mole of CuSO鈧 in a litre of solution, providing you with 1 mole of \(\text{Cu}^{2+}\) ions available for electrochemical reactions.

**Key Takeaways**:
  • **Dissociation**: CuSO鈧 dissociates completely in water, supplying ions required for the electrolysis process.
  • **Versatility**: It is used widely in industrial electroplating and as a precursor chemical in various copper-related chemical reactions.
Molarity calculation
Molarity is a way to express the concentration of a solution and is defined as the number of moles of solute per litre of solution. In this exercise, the initial molarity of the CuSO鈧 solution is 1 M, which means 1 mole of CuSO鈧 is dissolved in 1 litre of solution, giving us 1 mole of \(\text{Cu}^{2+}\) ions.

During the electrolysis process, the \\(\text{Cu}^{2+}\) ions from the CuSO鈧 solution gain electrons and are deposited as copper metal. As per the exercise, the entire 1 mole of Cu虏鈦 ions is used up, leaving no ions in the solution. This means we end up with a 0 M concentration of CuSO鈧 in the solution.
  • **Calculation Simplified**: If all \(\text{Cu}^{2+}\) ions are converted into copper metal, the final molarity is the initial molarity (1 M) minus the amount of substance removed, which in this case leaves us with 0 M.
Electrochemical reactions
Electrochemical reactions involve the movement of electrons, which induces chemical transformations during electrolysis. In our specific electrolysis setup, when electricity passes through the CuSO鈧 solution, \(\text{Cu}^{2+}\) ions receive electrons (reduction) at the cathode and become copper metal.

The balanced chemical reaction for this process is \\(\text{Cu}^{2+} + 2e^{-} \rightarrow \text{Cu}^0\). This shows that each copper ion requires exactly 2 electrons to be deposited as metal.

Understanding electrochemical reactions is crucial because:
  • **Reaction Clarity**: It outlines which species are reduced and oxidized. Here, copper is reduced, and the electrical energy facilitates this transformation.
  • **Industries and Applications**: Electrochemical reactions form the basis of many industrial processes, including metal plating, battery design, and spontaneous chemical processes like corrosion.

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Most popular questions from this chapter

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