Chapter 8: Problem 43
The compound whose \(0.1 \mathrm{M}\) solution is basic is (a) ammonium acetate (b) ammonium sulphate (c) sodium acetate (d) ammonium chloride
Short Answer
Expert verified
Sodium acetate makes the solution basic.
Step by step solution
01
Identify Compound Types
To determine which compound forms a basic solution, first recall that a basic solution has a pH greater than 7. Compounds that make a solution basic usually dissociate in water to produce hydroxide ions (OH鈦). We need to identify the nature of each compound: acid, base, or neutral salt.
02
Analyze Ammonium Acetate
Ammonium acetate (CH鈧僀OONH鈧) is a salt of a weak acid (acetic acid, CH鈧僀OOH) and a weak base (ammonium hydroxide, NH鈧凮H). It slightly hydrolyzes in water but usually remains at or near neutral pH.
03
Analyze Ammonium Sulphate
Ammonium sulphate
(NH鈧)鈧係O鈧
is a salt of a strong acid (sulfuric acid, H鈧係O鈧) and a weak base (NH鈧凮H). Its solution tends to be slightly acidic due to the release of NH鈧勨伜 ions, which are acidic.
04
Analyze Sodium Acetate
Sodium acetate (CH鈧僀OONa) is a salt from a weak acid (acetic acid, CH鈧僀OOH) and a strong base (sodium hydroxide, NaOH). It dissociates in water, and the resulting acetate ion (CH鈧僀OO鈦) acts as a weak base, making the solution basic.
05
Analyze Ammonium Chloride
Ammonium chloride (NH鈧凜l) is a salt of a strong acid (hydrochloric acid, HCl) and a weak base (NH鈧凮H). Its solution tends to be acidic due to the presence of NH鈧勨伜 ions that release H鈦 ions.
06
Select the Compound with Basic Solution
From the analyses, sodium acetate is the compound that, in a 0.1 M solution, would result in a basic pH due to its formation of acetate ions, which are basic.
Unlock Step-by-Step Solutions & Ace Your Exams!
-
Full Textbook Solutions
Get detailed explanations and key concepts
-
Unlimited Al creation
Al flashcards, explanations, exams and more...
-
Ads-free access
To over 500 millions flashcards
-
Money-back guarantee
We refund you if you fail your exam.
Over 30 million students worldwide already upgrade their learning with 91影视!
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Understanding Acid-Base Chemistry
Acid-base chemistry is a fascinating branch of chemistry that deals with the properties of acids, bases, and their interactions. Here, the pH scale is crucial in determining whether a solution is acidic, neutral, or basic.
Acids are substances that release hydrogen ions (\(H^+\)) in solutions, while bases release hydroxide ions (\(OH^-\)). When acids and bases interact in water, they can undergo neutralization reactions. This involves an acid and a base reacting to form water and a salt.
Acids are substances that release hydrogen ions (\(H^+\)) in solutions, while bases release hydroxide ions (\(OH^-\)). When acids and bases interact in water, they can undergo neutralization reactions. This involves an acid and a base reacting to form water and a salt.
- **Acid**: Typically characterized by sour taste and low pH (less than 7).
- **Base**: Generally has a bitter taste and slippery feel with a high pH (greater than 7).
- **Neutral Substances**: Have a pH close to 7, like pure water.
Exploring Hydrolysis of Salts
Hydrolysis is a chemical process involving the reaction of a substance with water. In the context of salts, hydrolysis can significantly affect the pH of a solution, depending on the nature of the acid and base from which the salt was derived.
When salts dissolve in water, they disassociate into their constituent ions. These ions can react with the water, leading to hydrolysis.
When salts dissolve in water, they disassociate into their constituent ions. These ions can react with the water, leading to hydrolysis.
- **Salt of Weak Acid and Strong Base**: Produces a basic solution, as the anion from the weak acid accepts a proton from water.
- **Salt of Strong Acid and Weak Base**: Results in an acidic solution, as the cation releases a proton to water.
- **Salt of Weak Acid and Weak Base**: Such solutions can be slightly acidic, basic, or neutral, depending on the relative strengths of the acid and base.
Decoding the pH Scale
The pH scale is an indispensable tool in chemistry, measuring how acidic or basic a solution is on a scale that usually ranges from 0 to 14. This logarithmic scale is a measure of the hydrogen ion concentration in a solution.
- **pH 0-6**: Indicates an acidic solution, where more free hydrogen ions (\(H^+\)) exist.
- **pH 7**: Represents a neutral solution, which contains equal numbers of hydrogen and hydroxide ions.
- **pH 8-14**: Indicates a basic solution with more hydroxide ions (\(OH^-\)).
Characteristics of Weak Acids and Bases
Weak acids and bases do not fully dissociate in water. Instead, they establish an equilibrium between undissociated molecules and ions in the solution.
For weak acids like acetic acid, only some molecules release (\(H^+\)) ions:
\[ \text{CH}_3\text{COOH} \rightleftharpoons \text{CH}_3\text{COO}^- + \text{H}^+ \]Likewise, weak bases like ammonium hydroxide have limited formation of (\(OH^-\)) ions:
\[ \text{NH}_4\text{OH} \rightleftharpoons \text{NH}_4^+ + \text{OH}^- \]
These partial ionization reactions make weak acids and bases sensitive to environmental pH changes and often involved in hydrolysis. Sodium acetate forms through a strong base (sodium hydroxide) and weak acid (acetic acid), with its conditions promoting a rise in pH, categorizing it as basic.
For weak acids like acetic acid, only some molecules release (\(H^+\)) ions:
\[ \text{CH}_3\text{COOH} \rightleftharpoons \text{CH}_3\text{COO}^- + \text{H}^+ \]Likewise, weak bases like ammonium hydroxide have limited formation of (\(OH^-\)) ions:
\[ \text{NH}_4\text{OH} \rightleftharpoons \text{NH}_4^+ + \text{OH}^- \]
These partial ionization reactions make weak acids and bases sensitive to environmental pH changes and often involved in hydrolysis. Sodium acetate forms through a strong base (sodium hydroxide) and weak acid (acetic acid), with its conditions promoting a rise in pH, categorizing it as basic.