Chapter 8: Problem 1
Which of these can not be a bronsted acid? (a) \(\mathrm{HCO}_{3}^{-}\) (b) \(\mathrm{HCOO}^{-}\) (c) \(\mathrm{H}_{2} \mathrm{PO}_{3}^{-}\) (d) \(\mathrm{H}_{3} \mathrm{O}^{+}\)
Short Answer
Step by step solution
Define a Bronsted Acid
Identify Proton Donors
Evaluate \\ \( \mathrm{HCO}_{3}^{-} \\)
Evaluate \\ \( \mathrm{HCOO}^{-} \\)
Evaluate \\ \( \mathrm{H}_{2} \mathrm{PO}_{3}^{-} \\)
Evaluate \\ \( \mathrm{H}_{3} \mathrm{O}^{+} \\)
Determine the Non-Bronsted Acid
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Proton Donor
This hydrogen atom becomes a proton when it is lost from the molecule.
When a compound donates a proton, it is converted into its conjugate base. The role of a proton donor can be found across numerous reactions, including acid-base chemistry, where the transfer of protons determines the behavior and strength of an acid compared to a base.
- A proton donor always has hydrogen as part of its structure.
- Often, the ability to donate a proton depends on the stability of the resulting conjugate base.
- This concept explains why some substances act as acids in specific reactions.
Bicarbonate Ion
Bicarbonate can release a proton to form the carbonate ion \( \mathrm{CO}_{3}^{2-} \), a process that identifies it as an acid in acid-base reactions. This property is crucial, as bicarbonate acts as a buffer in solutions, helping to maintain pH levels by neutralizing excess acids or bases.
- In water, bicarbonate helps balance pH by donating protons.
- As a conjugate base of carbonic acid, it plays a vital role in biological systems, helping transport carbon dioxide.
- Its amphiprotic nature allows it to convert to either carbonate or carbonic acid, depending on the conditions.
Hydronium Ion
This ability makes it a critical component in the behavior of acids in aqueous solutions, where the level of hydronium ions determines the solution's pH.
In any acidic solution, the hydronium ion is a significant contributor to the acidity, representing the abundance of protons that have been donated by acids:
- Hydronium ions are generated when an acid dissolves in water.
- This ion is significant for measuring the acidity (or pH) of a solution.
- It's crucial in various biological and chemical processes, influencing how reactions occur in aqueous environments.