Chapter 34: Problem 151
Match the following a. \(\mathrm{AgNO}_{3}+\mathrm{NaCNS}\) (p) White b. \(\mathrm{AgNO}_{3}+\mathrm{Na}_{3} \mathrm{PO}_{4}\) (q) Black c. \(\mathrm{AgNO}_{3}+\mathrm{K}_{2} \mathrm{CrO}_{4}\) (r) Brick red d. \(\mathrm{AgNO}_{3}+\mathrm{Na}_{3} \mathrm{~S}\) (s) Yellow
Short Answer
Expert verified
a-p: White, b-s: Yellow, c-r: Brick red, d-q: Black
Step by step solution
01
Identify Possible Products
When mixing each of the given reagents with \( \mathrm{AgNO}_3 \), silver salts will form. Silver salts are generally insoluble in water, resulting in a precipitate of a certain color, which is the key to matching.
02
Match Reactions with Outcomes for Silver Cyanide
For the reaction \( \mathrm{AgNO}_3 + \mathrm{NaCNS} \), \( \mathrm{AgCNS} \) is produced. Silver cyanide (\( \mathrm{AgCNS} \)) forms a precipitate that is white in color.
03
Match Reactions with Outcomes for Silver Phosphate
In the reaction \( \mathrm{AgNO}_3 + \mathrm{Na}_3 \mathrm{PO}_4 \), silver phosphate (\( \mathrm{Ag_3PO_4} \)) is produced, which forms a yellow precipitate.
04
Match Reactions with Outcomes for Silver Chromate
The reaction \( \mathrm{AgNO}_3 + \mathrm{K}_2 \mathrm{CrO}_4 \) produces silver chromate (\( \mathrm{Ag_2CrO_4} \)), resulting in a brick red precipitate.
05
Match Reactions with Outcomes for Silver Sulfide
For \( \mathrm{AgNO}_3 + \mathrm{Na}_3 \mathrm{~S} \), silver sulfide (\( \mathrm{Ag_2S} \)) forms a precipitate that is black in color.
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Silver Cyanide
In the world of chemistry, Silver Cyanide (\(\text{AgCNS}\)) is a compound formed when silver nitrate (\(\text{AgNO}_3\)) reacts with sodium cyanide (\(\text{NaCNS}\)). This reaction results in a white precipitate. Here's why and how it happens:
- **Reaction Process**: When \(\text{AgNO}_3\) and \(\text{NaCNS}\) are mixed, they exchange ions to form \(\text{AgCNS}\) and sodium nitrate (\(\text{NaNO}_3\)).
- **Precipitation**: Silver cyanide is not soluble in water, which leads to the formation of a solid precipitate. This is a crucial aspect of precipitation reactions—when a compound does not dissolve in water, it appears as a distinct solid.
- **Visual Cue**: The white color of the \(\text{AgCNS}\) precipitate makes it easily identifiable in lab experiments. Recognizing and understanding the role of color in these reactions is an essential skill in chemistry.
- **Reaction Process**: When \(\text{AgNO}_3\) and \(\text{NaCNS}\) are mixed, they exchange ions to form \(\text{AgCNS}\) and sodium nitrate (\(\text{NaNO}_3\)).
- **Precipitation**: Silver cyanide is not soluble in water, which leads to the formation of a solid precipitate. This is a crucial aspect of precipitation reactions—when a compound does not dissolve in water, it appears as a distinct solid.
- **Visual Cue**: The white color of the \(\text{AgCNS}\) precipitate makes it easily identifiable in lab experiments. Recognizing and understanding the role of color in these reactions is an essential skill in chemistry.
Silver Phosphate
Silver Phosphate (\(\text{Ag}_3\text{PO}_4\)) results from the reaction between silver nitrate (\(\text{AgNO}_3\)) and trisodium phosphate (\(\text{Na}_3\text{PO}_4\)). This process generates a yellow precipitate, which is a classic demonstration in chemistry.
- **Reaction Equation**: The combination of these compounds can be represented as follows:
\[3\text{AgNO}_3 + \text{Na}_3\text{PO}_4 \rightarrow \text{Ag}_3\text{PO}_4 + 3\text{NaNO}_3\]
- **Mechanism**: As a result of the ionic exchange, the silver ions (\(\text{Ag}^+\)) pair with phosphate ions (\(\text{PO}_4^{3-}\)), forming the yellow \(\text{Ag}_3\text{PO}_4\) solid.
- **Properties**: One interesting property of silver phosphate is its photoluminescent quality. Under certain conditions, it can glow, which adds another layer of intrigue to this compound.
- **Application and Use**: Silver phosphate's distinctive yellow precipitate helps chemists separate it from other compounds in a mixture, making it useful in analytical chemistry.
- **Reaction Equation**: The combination of these compounds can be represented as follows:
\[3\text{AgNO}_3 + \text{Na}_3\text{PO}_4 \rightarrow \text{Ag}_3\text{PO}_4 + 3\text{NaNO}_3\]
- **Mechanism**: As a result of the ionic exchange, the silver ions (\(\text{Ag}^+\)) pair with phosphate ions (\(\text{PO}_4^{3-}\)), forming the yellow \(\text{Ag}_3\text{PO}_4\) solid.
- **Properties**: One interesting property of silver phosphate is its photoluminescent quality. Under certain conditions, it can glow, which adds another layer of intrigue to this compound.
- **Application and Use**: Silver phosphate's distinctive yellow precipitate helps chemists separate it from other compounds in a mixture, making it useful in analytical chemistry.
Silver Chromate
In a fascinating display of chemistry, the reaction of silver nitrate (\(\text{AgNO}_3\)) and potassium chromate (\(\text{K}_2\text{CrO}_4\)) yields silver chromate (\(\text{Ag}_2\text{CrO}_4\)), which is known for forming a brick red precipitate.
- **Reaction Details**: The chemical equation for this reaction is as follows:
\[2\text{AgNO}_3 + \text{K}_2\text{CrO}_4 \rightarrow \text{Ag}_2\text{CrO}_4 + 2\text{KNO}_3\]
- **Understanding the Process**: The key change here is the exchange of ions, where silver ions meet chromate ions. The result is silver chromate, which forms a noticeable red solid.
- **Color Significance**: The color difference in these reactions helps in visually identifying the product just by observation, a crucial factor for chemists.
- **Practical Usage**: Silver chromate's red precipitate is not only useful for identification but also for its applications in electrochemical sensors, due to its distinct appearance and reactivity.
- **Reaction Details**: The chemical equation for this reaction is as follows:
\[2\text{AgNO}_3 + \text{K}_2\text{CrO}_4 \rightarrow \text{Ag}_2\text{CrO}_4 + 2\text{KNO}_3\]
- **Understanding the Process**: The key change here is the exchange of ions, where silver ions meet chromate ions. The result is silver chromate, which forms a noticeable red solid.
- **Color Significance**: The color difference in these reactions helps in visually identifying the product just by observation, a crucial factor for chemists.
- **Practical Usage**: Silver chromate's red precipitate is not only useful for identification but also for its applications in electrochemical sensors, due to its distinct appearance and reactivity.
Silver Sulfide
Silver Sulfide (\(\text{Ag}_2\text{S}\)) is the product of the reaction between silver nitrate (\(\text{AgNO}_3\)) and sodium sulfide (\(\text{Na}_3\text{S}\)). This reaction forms a striking black precipitate.
- **Chemical Equation**: The reaction can be expressed as:
\[2\text{AgNO}_3 + \text{Na}_2\text{S} \rightarrow \text{Ag}_2\text{S} + 2\text{NaNO}_3\]
- **Precipitate Formation**: Silver sulfide's insolubility in water causes it to form a dark solid during the reaction.
- **Natural Occurrence**: This compound is known to form naturally as tarnish on silverware, when silver reacts with sulfur-containing substances in the air.
- **Applications**: Aside from its notable color, silver sulfide is also interesting because of its electrical properties. It is used in the production of infrared detectors and as a semiconductor.
- **Color Understanding**: Recognizing the black color of silver sulfide precipitate helps distinguish it during chemical analysis, which is a fundamental skill in conducting and interpreting chemical reactions.
- **Chemical Equation**: The reaction can be expressed as:
\[2\text{AgNO}_3 + \text{Na}_2\text{S} \rightarrow \text{Ag}_2\text{S} + 2\text{NaNO}_3\]
- **Precipitate Formation**: Silver sulfide's insolubility in water causes it to form a dark solid during the reaction.
- **Natural Occurrence**: This compound is known to form naturally as tarnish on silverware, when silver reacts with sulfur-containing substances in the air.
- **Applications**: Aside from its notable color, silver sulfide is also interesting because of its electrical properties. It is used in the production of infrared detectors and as a semiconductor.
- **Color Understanding**: Recognizing the black color of silver sulfide precipitate helps distinguish it during chemical analysis, which is a fundamental skill in conducting and interpreting chemical reactions.