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Kinetic energy per mole of an ideal gas is (a) Zero at zero Kelvin temperature (b) Independent of temperature (c) Proportional to the absolute temperature of the gas (d) Proportional to pressure at constant temperature

Short Answer

Expert verified
The correct answer is (c): Kinetic energy is proportional to the absolute temperature of the gas.

Step by step solution

01

Understanding Kinetic Energy of an Ideal Gas

The kinetic energy per mole of an ideal gas is related to its temperature. In kinetic theory, the average kinetic energy of gas particles is directly proportional to the absolute temperature measured in Kelvin. This can be modeled by the equation for kinetic energy for one mole: \( KE_{mole} = \frac{3}{2}RT \), where \( R \) is the universal gas constant and \( T \) is the absolute temperature.
02

Evaluating Option (a)

Option (a) states that kinetic energy is zero at zero Kelvin. This is true because at absolute zero, particle motion theoretically stops, implying no kinetic energy. However, this does not describe the general relationship asked in the exercise, just the condition at a specific point.
03

Evaluating Option (b)

Option (b) states that kinetic energy is independent of temperature. This is incorrect because we know from kinetic theory that kinetic energy is directly proportional to temperature; they are fundamentally linked.
04

Evaluating Option (c)

Option (c) states that kinetic energy is proportional to the absolute temperature of the gas. This is correct, as it accurately describes the relationship given by \( KE_{mole} = \frac{3}{2}RT \). The kinetic energy increases linearly with temperature.
05

Evaluating Option (d)

Option (d) states that kinetic energy is proportional to pressure at constant temperature. Kinetic energy is related to temperature, not directly to pressure. At constant temperature, pressure change does not impact kinetic energy, making this option incorrect.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Kinetic Theory of Gases
The Kinetic Theory of Gases is a fundamental concept that describes gases as composed of many small particles, most often atoms or molecules, which are in constant, random motion. This theory is essential for understanding how gases behave under different conditions and forms the foundation for many other theoretical models in chemistry and physics. Here are some key principles of the kinetic theory of gases:
  • Gas particles are in continuous, random motion, colliding with each other and the walls of their container.
  • These collisions with the walls of the container are what we perceive as gas pressure.
  • The average kinetic energy of gas particles is proportional to the absolute temperature of the gas.
The relationship between temperature and kinetic energy is particularly significant. As the temperature of a gas increases, the average kinetic energy of its particles also increases, resulting in more energetic collisions. This relationship explains why gases expand when heated, as the increased collisions result in higher pressure that, if the container is flexible, pushes its walls outward. Understanding these concepts helps us explain phenomena like pressure changes and gas diffusion in a straightforward manner.
Absolute Temperature
Absolute temperature is a way of expressing temperature using an absolute scale, meaning it starts at absolute zero. Absolute zero is the point at which particles theoretically have minimal motion and kinetic energy. The Kelvin scale is the most commonly used absolute temperature scale in scientific contexts. Unlike the Celsius and Fahrenheit scales, the Kelvin scale does not use degrees. Zero Kelvin is absolute zero, and the increments are the same as those on the Celsius scale. Absolute temperature is crucial for calculations in physics and chemistry because it provides a direct measure of the energy in a system. It allows scientists to understand and predict the behavior of gases better, as the kinetic energy and hence many properties of gases depend directly on temperature. If you have a gas at a particular temperature in Kelvin, you can expect its properties to change proportionally as you increase or decrease that temperature due to these dependencies.
Universal Gas Constant
The Universal Gas Constant, denoted by the symbol \( R \), is a key element in the study of gases and thermodynamics. It appears in the ideal gas law equation, which describes the state of an ideal gas using the formula: \[ PV = nRT \]where \( P \) is pressure, \( V \) is volume, \( n \) is the number of moles, and \( T \) is the absolute temperature.The universal gas constant is a bridge that connects energy scales with temperature within the context of the ideal gas law. In the formula for the kinetic energy per mole of gas, \( KE_{mole} = \frac{3}{2}RT \), \( R \) effectively scales the temperature to match the energy measurements, showing that energy increases with temperature. Its value is fixed and universal, meaning it applies to any ideal gas, providing consistency in calculations across different conditions and systems. This consistency is invaluable for engineers, chemists, and physicists who need to model and predict the behavior of gases in a wide array of experimental and real-world applications.

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Most popular questions from this chapter

An L.P.G. cylinder contains \(15 \mathrm{~kg}\) of butane gas at \(27^{\circ} \mathrm{C}\) and 10 atmospheric pressure. It was leaking and its pressure fell down to 8 atmospheric pressure after one day. The gas leaked in 5 days is (a) \(10 \mathrm{~kg}\) (b) \(3 \mathrm{~kg}\) (c) \(15 \mathrm{~kg}\) (d) \(12 \mathrm{~kg}\)

At constant volume and temperature conditions, the rates of diffusion \(\mathrm{D}_{\mathrm{A}}\) and \(\mathrm{D}_{\mathrm{B}}\) of gases \(\mathrm{A}\) and \(\mathrm{B}\) having densities \(\rho_{A}\) and \(\rho_{B}\) are related by the expression (a) \(\mathrm{D}_{A}=\left[\mathrm{D}_{\mathrm{B}} \rho_{\mathrm{A}} / \rho_{\mathrm{B}}\right]^{1 / 2}\) (b) \(\mathrm{D}_{\mathrm{A}}=\left[\mathrm{D}_{\mathrm{B}} \rho_{\mathrm{B}} / \rho_{\mathrm{A}}\right]^{1 / 2}\) (c) \(\mathrm{D}_{A}=\mathrm{D}_{\mathrm{B}}\left[\rho_{\mathrm{A}} / \rho_{\mathrm{B}}\right]^{1 / 2}\) (d) \(\mathrm{D}_{\mathrm{A}}=\mathrm{D}_{\mathrm{B}}\left[\rho_{\mathrm{B}} / \rho_{\mathrm{A}}\right]^{1 / 2}\)

An ideal gas obeying kinetic gas equation can be liquefied if (a) it cannot be liquefi ed at any value of \(\mathrm{P}\) and \(\mathrm{T}\) (b) its temperature is more than Boyle's temperature (c) its temperature is more than critical temperature (d) its pressure is more than critical pressure

Four rubber tubes are respectively filled with \(\mathrm{H}_{2}, \mathrm{He}\), \(\mathrm{N}_{2}\) and \(\mathrm{O}_{2} .\) Which tube will be reinflated first? (a) \(\mathrm{H}_{2}\) filled tube (b) \(\mathrm{N}_{2}\) filled tube (c) He filled tube (d) \(\mathrm{O}_{2}\) filled tube

At \(25^{\circ} \mathrm{C}\) and \(730 \mathrm{~mm}\) pressure, \(380 \mathrm{~mL}\) of dry oxygen was collected. If the temperature is constant, what volume will the oxygen occupy at \(760 \mathrm{~mm}\) pressure? (a) \(365 \mathrm{~mL}\) (b) \(2 \mathrm{~mL}\) (c) \(10 \mathrm{~mL}\) (d) \(20 \mathrm{~mL}\)

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