Chapter 17: Problem 139
The pair of compounds which cannot exist together in aqueous solution is (a) \(\mathrm{NaH}_{2} \mathrm{PO}_{4}\) and \(\mathrm{Na}_{2} \mathrm{HCO}_{3}\) (b) \(\mathrm{Na}_{2} \mathrm{CO}_{3}\) and \(\mathrm{NaHCO}_{3}\) (c) \(\mathrm{NaOH}\) and \(\mathrm{NaH}_{2} \mathrm{PO}_{4}\) (d) \(\mathrm{NaHCO}_{3}\) and \(\mathrm{NaOH}\)
Short Answer
Step by step solution
Identify the Properties of Each Compound
Analyze Acid-Base Reactions
Evaluate Pair (a)
Evaluate Pair (b)
Evaluate Pair (c)
Evaluate Pair (d)
Conclusion
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chemical Properties
On the other hand, sodium bicarbonate ( NaHCO_3 ) acts as a weak base, with less impact on pH compared to stronger bases. This difference in chemical properties influences how these compounds interact in aqueous solutions.
- Acids release hydrogen ions ( H^+ ), making the solution more acidic.
- Bases accept hydrogen ions, making the solution more basic.
- The strength of an acid or base is determined by its degree of dissociation in water.
Buffer Systems
For instance, the carbonate buffer system involving sodium bicarbonate ( NaHCO_3 ) and sodium carbonate ( Na_2CO_3 ) demonstrates how buffers operate. When an acid is added, the bicarbonate neutralizes it by forming carbonic acid, while adding a base would convert bicarbonate into carbonate, stabilizing pH levels. This resilience to pH change is indispensable in biological systems and many industrial and chemical processes.
- Buffers can only mitigate changes within a particular range, specific to the buffer pair.
- The effectiveness of a buffer is characterized by its buffer capacity.
- Buffers in living organisms are crucial for maintaining homeostasis.
Aqueous Solutions
When a solution contains weak and strong acids or bases, reactions often occur that can alter the availability of the original substances. For example, a strong base like sodium hydroxide ( NaOH ) in water will almost completely dissociate, potentially affecting weak acids or bases in the solution. This interaction may cause a chemical change, preventing the coexistence of the initial compounds. In the case of sodium bicarbonate ( NaHCO_3 ) with sodium hydroxide, the latter would convert it into forming stronger bases, leading them to no longer coexist in their original forms.
- Aqueous solutions provide a medium for ionic interactions.
- The solubility and dissociation levels of compounds in water are crucial for predicting behavior in solutions.
- Accurate predictions of reactions and stability require an understanding of both the solute properties and the solvent’s characteristics.