Chapter 16: Problem 13
Mark the wrong statement which of the following statements about/regarding \(\mathrm{BF}_{3}\) is incorrect? (a) it forms an addition compound with \(\mathrm{NH}_{3}\) (b) it is a volatile liquid at room temperature (c) it combines with either to form boron trifluoride etherate (d) it acts as a Lewis acid
Short Answer
Step by step solution
Analyze Statement (a)
Analyze Statement (b)
Analyze Statement (c)
Analyze Statement (d)
Conclusion: Identify Incorrect Statement
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Lewis Acid
When \( \mathrm{BF}_{3} \) interacts with a Lewis base, such as ammonia (\( \mathrm{NH}_{3} \)), it readily forms a coordinate covalent bond. This bond occurs when the nitrogen atom from \( \mathrm{NH}_{3} \), which has a lone pair of electrons, donates this pair to the boron atom in \( \mathrm{BF}_{3} \).
- \( \mathrm{BF}_{3} \) has three covalent bonds with fluorine atoms, but the boron atom lacks a full octet of electrons.
- This deficiency makes boron very reactive with substances that can provide electron pairs.
- The resultant complex from \( \mathrm{BF}_{3} \) and \( \mathrm{NH}_{3} \) is called \( \mathrm{F}_{3}\mathrm{B} - \mathrm{NH}_{3} \).
Addition Compound
\( \mathrm{F}_{3}\mathrm{B} - \mathrm{NH}_{3} \) showcases the Lewis acid-base interaction vividly as the electron-deficient boron atom accepts electrons from the lone pair of \( \mathrm{NH}_{3} \). This process stabilizes both molecules into a new complex.
- The new bond between boron and nitrogen involves the sharing of the donated electron pair.
- It's through these interactions that many new and useful compounds are synthesized in the chemical industry.
- The resulting compound has different properties compared to its individual components.
Volatile Liquid
The term 'volatile' can often lead to misconceptions about the state of certain compounds. While \( \mathrm{BF}_{3} \) is indeed volatile, it's crucial to note:
- \( \mathrm{BF}_{3} \) is found as a gas under standard room conditions, not a liquid.
- When discussing chemicals, differentiating between a gas and a volatile liquid is important for understanding their physical behavior.
- Mistaken classification of \( \mathrm{BF}_{3} \) as a liquid can lead to errors in laboratory or industrial applications.