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Hydrogen peroxide acts both as an oxidising and as a reducing agent depending upon the nature of the reacting species. In which of the following cases \(\mathrm{H}_{2} \mathrm{O}_{2}\) acts as a reducing agent in acid medium? (a) \(\mathrm{MnO}_{4}^{-}\) (b) \(\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}\) (c) \(\mathrm{SO}_{3}^{2-}\) (d) \(\mathrm{KI}\)

Short Answer

Expert verified
H鈧侽鈧 acts as a reducing agent with (a) MnO鈧勨伝 and (b) Cr鈧侽鈧嚶测伝.

Step by step solution

01

Understand the Role of Reducing Agents

A reducing agent is a substance that donates electrons to another substance, causing the latter to be reduced while the reducing agent itself is oxidized. In the context of this problem, it involves identifying which reacting species causes the oxidation of hydrogen peroxide (H鈧侽鈧) in an acid medium.
02

Analyze Permanganate Ion ( \(\mathrm{MnO}_{4}^{-} \))

In an acidic medium, \(\mathrm{MnO}_{4}^{-}\) acts as a strong oxidizing agent. When it reacts with H鈧侽鈧, it is reduced to Mn虏鈦. Hence, in this reaction, H鈧侽鈧 will be oxidized, acting as a reducing agent.
03

Analyze Dichromate Ion ( \(\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-} \))

\(\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}\) in an acidic medium is also a strong oxidizing agent, converting Cr鈦垛伜 to Cr鲁鈦. H鈧侽鈧 can act as a reducing agent by providing electrons for this reduction.
04

Analyze Sulfite Ion ( \(\mathrm{SO}_{3}^{2-} \))

In an acidic medium, \(\mathrm{SO}_{3}^{2-}\) would more often react as a reducing agent, being oxidized to \(\mathrm{SO}_{4}^{2-}\). Therefore, it is less likely for H鈧侽鈧 to act as a reducing agent in this scenario.
05

Analyze Potassium Iodide ( \(\mathrm{KI} \))

In an acidic medium, KI can be oxidized to I鈧 while H鈧侽鈧 would be reduced. In this reaction, H鈧侽鈧 acts as an oxidizing agent, not a reducing agent.
06

Conclusion

Based on the analysis, H鈧侽鈧 acts as a reducing agent when reacting with \(\mathrm{MnO}_{4}^{-}\) and \(\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}\), as these species are reduced while H鈧侽鈧 is oxidized.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Oxidizing Agent
An oxidizing agent is a substance that accepts electrons from another chemical species during a redox reaction. This means it causes another species to be oxidized while it is reduced. Oxidizing agents are essential in redox reactions because they drive the transfer of electrons between substances. Some common examples include
  • permanganate ions (\(\mathrm{MnO}_{4}^{-}\)),
  • dichromate ions (\(\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}\)),
  • and oxygen.
In the case of hydrogen peroxide (\(\mathrm{H}_{2} \mathrm{O}_{2}\)), when it interacts with a strong oxidizing agent like \(\mathrm{MnO}_{4}^{-}\) or \(\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}\), the latter compounds are reduced, thus transforming into Mn虏鈦 and Cr鲁鈦 respectively.
This process includes a redox reaction where the oxidizing agent "pulls" electrons from hydrogen peroxide, which functions as the reducing agent by losing electrons.
Reducing Agent
A reducing agent is a substance that loses electrons in a redox reaction, thereby causing another substance to be reduced. When a reducing agent donates electrons, it itself becomes oxidized. This concept is the reverse of how oxidizing agents work; instead of gaining electrons, a reducing agent gives them away.
  • Hydrogen peroxide (\(\mathrm{H}_{2} \mathrm{O}_{2}\)) can act as a reducing agent when it reacts with strong oxidizing agents.
  • This includes substances like permanganate ions and dichromate ions.
In reactions where \(\mathrm{MnO}_{4}^{-}\) or \(\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}\) are involved, \(\mathrm{H}_{2} \mathrm{O}_{2}\) donates electrons to these agents, resulting in the oxidation of \(\mathrm{H}_{2} \mathrm{O}_{2}\) itself.
The primary focus when identifying a reducing agent is to observe which substance in a reaction loses electrons during the chemical transformation.
Hydrogen Peroxide in Acidic Medium
Hydrogen peroxide (\(\mathrm{H}_{2} \mathrm{O}_{2}\)) is an interesting compound because it can function as either an oxidizing or reducing agent depending on the chemical environment and reactants present. It is particularly versatile when used in an acidic medium. Acidic conditions often facilitate and enhance redox reactions by providing the necessary H鈦 ions.
In an acidic medium, reactions with oxidizing agents like \(\mathrm{MnO}_{4}^{-}\) or \(\mathrm{Cr}_{2} \mathrm{O}_{7}^{2-}\) result in hydrogen peroxide acting primarily as a reducing agent.
  • The acidic medium helps in the efficient transfer of electrons.
  • It also stabilizes the charged ions formed during these redox reactions.
The transformation of these oxidizing agents from higher oxidation states to lower ones, accompanied by the oxidation of \(\mathrm{H}_{2} \mathrm{O}_{2}\), showcases the dynamic role hydrogen peroxide plays in these reactions. Understanding how \(\mathrm{H}_{2} \mathrm{O}_{2}\) operates can help predict its behavior in various chemical settings.

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