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Thermal decomposition of a Mn compound (X) at \(513 \mathrm{~K}\) results in compound \(\mathrm{Y}, \mathrm{MnO}_{2}\) and a gaseous product. \(\mathrm{MnO}_{2}\) reacts with \(\mathrm{NaCl}\) and concentrated \(\mathrm{H}_{2} \mathrm{SO}_{4}\) to give a pungent gas \(\mathrm{Z} . \mathrm{X}, \mathrm{Y}\), and \(\mathrm{Z}\), respectively, are: (a) \(\mathrm{KMnO}_{4}, \mathrm{~K}_{2} \mathrm{MnO}_{4}\) and \(\mathrm{Cl}_{2}\) (b) \(\mathrm{K}_{2} \mathrm{MnO}_{4}, \mathrm{KMnO}_{4}\) and \(\mathrm{SO}_{2}\) (c) \(\mathrm{K}_{3} \mathrm{MnO}_{4}, \mathrm{~K}_{2} \mathrm{MnO}_{4}\) and \(\mathrm{Cl}_{2}\) (d) \(\mathrm{K}_{2} \mathrm{MnO}_{4}, \mathrm{KMnO}_{4}\) and \(\mathrm{Cl}_{2}\)

Short Answer

Expert verified
The correct sequence is (a): KMnO鈧, K鈧侻nO鈧, and Cl鈧.

Step by step solution

01

Identify Initial Compound X

The problem mentions that the compound X undergoes thermal decomposition, generating MnO鈧, a common decomposition result of permanganate compounds. This suggests compound X could be a permanganate, likely KMnO鈧.
02

Decomposition Reaction

When KMnO鈧 is heated, it decomposes to produce K鈧侻nO鈧 (compound Y), MnO鈧, and O鈧 as the gas. The equation for this reaction is: \[ 2 \text{KMnO}_4 \rightarrow \text{K}_2\text{MnO}_4 + \text{MnO}_2 + \text{O}_2 \] This aligns with compound Y being K鈧侻nO鈧.
03

Reaction with NaCl and H2SO4

The problem suggests that MnO鈧 reacts with NaCl and concentrated H鈧係O鈧 to generate a pungent gas. This reaction is known to yield chlorine gas (Cl鈧), a result of MnO鈧 acting as an oxidizing agent.
04

Verification and Comparison

From the reactions analyzed, we obtained that X is KMnO鈧, Y is K鈧侻nO鈧, and Z is the pungent gas Cl鈧. Per the provided options, the correct choice matching this conclusion is option (a), which lists X as KMnO鈧, Y as K鈧侻nO鈧, and Z as Cl鈧.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Permanganate Compounds
Permanganate compounds are fascinating substances known for their vibrant purple color in solutions and their significant chemical reactivity. These compounds typically contain the permanganate ion, MnO鈧勨伝.
One of the most common permanganate compounds is potassium permanganate (KMnO鈧). It's widely used in laboratories as a strong oxidizing agent. When heated to a temperature like 513 K, KMnO鈧 undergoes thermal decomposition. This means it breaks down into simpler substances due to the application of heat.
In the case of KMnO鈧, heating results in the formation of potassium manganate (K鈧侻nO鈧), manganese dioxide (MnO鈧), and the release of oxygen gas.
  • Potassium Permanganate (KMnO鈧): A purple salt, often used in titration due to its strong oxidizing properties and distinct color change.
  • Potassium Manganate (K鈧侻nO鈧): Green in color, it is one of the decomposition products of KMnO鈧.
This reaction is not only an example of thermal decomposition but also demonstrates the interconnected nature of different manganese compounds.
Oxidizing Agents
Oxidizing agents play a crucial role in numerous chemical reactions, including those involving permanganate compounds. An oxidizing agent is a substance that can accept electrons, thereby oxidizing another substance while itself being reduced.
Manganese dioxide (MnO鈧) is considered a strong oxidizing agent. This characteristic is evident when it reacts with sodium chloride (NaCl) and concentrated sulfuric acid (H鈧係O鈧). In this interaction, MnO鈧 oxidizes the chloride ions in NaCl to chlorine gas (Cl鈧), while itself getting reduced.
  • Manganese Dioxide (MnO鈧): Can be found as a product of KMnO鈧 decomposition, acting as an oxidizing agent in subsequent reactions.
  • Chlorine Gas (Cl鈧): A pungent gas released during the reaction, recognized for its distinctive smell and use as a disinfectant.
Understanding the behavior of oxidizing agents like MnO鈧 allows chemists to predict and control chemical transformations effectively.
Chemical Reactions at High Temperatures
Chemical reactions can be significantly influenced by high temperatures, often providing the necessary energy to initiate reactions that would otherwise be slow or non-spontaneous under normal conditions. High-temperature reactions are common in both industrial processes and educational demonstrations.
In the context of permanganate compounds, heating KMnO鈧 initiates its decomposition. This breakdown not only forms new compounds such as K鈧侻nO鈧 and MnO鈧 but also releases oxygen, showcasing the powerful effects of thermal energy.
High temperatures can lead to changes in chemical kinetics, affecting reaction rates and equilibrium. They can also enable reactions by overcoming activation energy barriers.
  • Decomposition of KMnO鈧: Requires substantial heat to convert the permanganate into magnesium dioxide and other products.
  • Role of Heat: It acts as a catalyst, increasing the energy available for bond breaking and formation in these reactions.
By understanding these principles, students and scientists can harness high temperatures to efficiently drive desired chemical changes.

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