Chapter 19: Problem 3
Match the catalysts to the correct processes:Catalyst Process (A) \(\mathrm{TiCl}_{4}\) (i) Wacker process (B) \(\mathrm{PdCl}_{2}\) (ii) Ziegler - Natta polymerization (C) \(\mathrm{CuCl}_{2}\) (iii) Contact process (D) \(\mathrm{V}_{2} \mathrm{O}_{5}\) (iv) Deacon's process (a) (A) - (ii), (B) - (iii), (C) - (iv), (D) - (i) (b) (A) - (iii), (B)-(i), (C) - (ii), (D) - (iv) (c) (A) - (iii), (B)-(ii), (C) - (iv), (D) - (i) (d) (A) - (ii), (B) - (i), (C) - (iv), (D) - (iii)
Short Answer
Step by step solution
Identify the Ziegler-Natta Polymerization Catalyst
Identify the Wacker Process Catalyst
Identify the Deacon's Process Catalyst
Identify the Contact Process Catalyst
Match Catalysts to Processes
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Ziegler-Natta Polymerization
The catalyst used in Ziegler-Natta polymerization is typically titanium tetrachloride, represented chemically as \( \mathrm{TiCl}_{4} \). This unique compound enables the polymerization process to occur at relatively low pressures and temperatures compared to other methods.
- Enhances the efficiency of the polymerization process.
- Allows control over the molecular weight of the resulting polymer.
- Enables the production of polymers with specific desired properties, such as strength and flexibility.
Wacker Process
In the Wacker process, the catalyst is palladium chloride, or \( \mathrm{PdCl}_{2} \), which helps facilitate the reaction. This catalyst acts as a medium to speed up the conversion of ethylene to acetaldehyde without being consumed in the process.
- Utilizes oxygen from the air, making it efficient and environmentally friendly.
- Operates under mild conditions, reducing energy requirements.
- The catalysis involves palladium cycling between different oxidation states.
Contact Process
In the contact process, vanadium(V) oxide, expressed as \( \mathrm{V}_{2} \mathrm{O}_{5} \), plays the role of the catalyst. This material assists in the oxidation of sulfur dioxide to sulfur trioxide, which is the critical step in sulfuric acid production.
- Operates at high temperatures to optimize the conversion rate.
- Allows for continuous production, enhancing industrial output.
- Ensures the effective utilization of raw materials.
Deacon's Process
In the Deacon's process, copper(II) chloride, \( \mathrm{CuCl}_{2} \), serves as the catalyst to convert hydrogen chloride and oxygen into chlorine and water. This process is one of the classic methods for chlorine production due to its effectiveness.
- Contributes to a green chemistry approach by recycling hydrogen chloride.
- Conveniently utilizes air as a source of oxygen.
- Allows for steady production of chlorine under controlled conditions.