Chapter 2: Problem 28
The hydrogen bonding that occurs in water is responsible for all of the following, except (a) the high boiling point of water, (b) the low freezing point of water, (c) the ability of water to dissolve nonpolar substances, (d) the ability of water to dissolve inorganic salts, (e) the surface tension of water.
Short Answer
Step by step solution
Understanding Hydrogen Bonding in Water
Evaluating Water's High Boiling Point
Evaluating Water's Freezing Point
Evaluating Water's Ability to Dissolve Nonpolar Substances
Evaluating Water's Ability to Dissolve Inorganic Salts
Evaluating Surface Tension of Water
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Boiling Point of Water
This is why water boils at 100°C, which is significantly higher than one might expect given its molecular weight.
Understanding this can help explain why water can remain a liquid over a wide temperature range, which is essential for life as we know it.
- Hydrogen bonds result in cohesive forces that increase water's boiling point.
- Boiling involves breaking these bonds so that molecules can enter the gas phase.
Solubility of Nonpolar Substances
This principle is often remembered by the phrase "like dissolves like," meaning polar solvents best dissolve polar solutes, and nonpolar solvents dissolve nonpolar solutes.
- Water's polarity does not match with nonpolar substances like oil or fats.
- Due to their mismatched polarities, nonpolar substances cannot mix well with water.
- Hydrophobic interactions are typical of nonpolar substances, causing them to separate in water.
Surface Tension of Water
This cohesion between molecules results in water having a higher surface tension than many other liquids.
The consequences of high surface tension are far-reaching, affecting everything from the formation of droplets to the ability of plants to draw water from their roots upward through a phenomenon known as capillary action.
- Hydrogen bonds pull water molecules close together at the surface.
- This creates a "film" that makes it difficult to break through the surface.
- Surface tension affects how liquids spread over surfaces and the ability of certain objects to float.